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Impact of Kishnica mines on pollution of the Graçanka River and water wells nearby, Kosovo

Kadriu Sadija, Sadiku Milaim, Kelmendi Mensur, Aliu Mehush, Mulliqi Ismet, Hyseni Arbër

Journal of Water and Land Development

2021

no. 48

16--21

Mining is an important economic activity in Kosovo. Artana and Kishnica mines are a part of the Trepça industrial complex and the increased exploitation of deposits has resulted in undesirable impact on the environment around the mining sites. More specifically, the mining activity caused water pollution. The aim of the study was to assess the physico-chemical parameters and presence of heavy metals (Ni, Zn, As, Cd, Pb, Cr, Mn, Fe) in water samples of the Graçanka River and household wells in the area. The Inductively Coupled Plasma-Mass Spectrometer (ICP-MS) was used to determine metal concentrations. Samples were collected from five sites along the Graçanka River and from four private water wells during a period from September to November 2019. Concentrations of heavy metals in the Graçanka River were as follows Mn (24–1203 μg∙dm–3), Fe (11–785 μg∙dm–3), Ni (4–299 μg∙dm–3), Pb (2–22 μg∙dm–3), As (1–5 μg∙dm–3), Zn (344–1646 μg∙dm–3), Cr (1–2 μg∙dm–3) and Cd (<1 μg∙dm–3). The well waters were polluted by multiple metals (Mn > Fe > Ni > Pb) with concentrations of Mn 1834–36089 μg∙dm–3, Fe 158–3535 μg∙dm–3, Ni 82–1882 μg∙dm–3, Pb 5–45 μg∙dm–3, As 2–19 μg∙dm–3, Cd 1–12 μg∙dm–3, Zn 979–23474 μg∙dm–3 and Cr 1–2 μg∙dm–3. The pollution has been caused by industrial (mining-related) and urban discharges. The contamination originates from the release of flotation process waste and from the leaching of the tailings dam. Most probably, rainwater has washed contaminants into the aquifers and the Graçanka River. River water is not suitable for irrigation and well water is not suitable for consumption or irrigation. Wastewater should be treated before discharge and the tailings area should be remediated in order to stop the pollution.

Scale of pollutions with heavy metals in water and sediment of River Ibër from landfill in Kelmend, Kosovo

Kadriu Sadija, Sadiku Milaim, Kelmendi Mensur, Mulliqi Ismet, Aliu Mehush, Hyseni Arbër

Mining Science

2019

Vol. 26

147--155

Pollution with heavy metals and waters in Mitrovica with surroundings, both in the past and in present days, is a preoccupation for the citizens of Mirtovica, as well as for the other inhabitants living around it. Such a problem has been a concern which still continues for a number of researchers who have been dealing with this issue, and who still continue to be preoccupied with the issue of heavy metal (habitat) pollution in this part of Kosovo. Heavy metal's contamination of the environment's main components, dates back to the 1970s/90s to this date. This pollution, especially of the rivers, is due to the industrial activity taking place in the Trepça Combine and the presence of industrial landfill sites of this Combine near the flow of two main rivers: the Sitnica and Ibër River waters, in the city of Mitrovica. The focus of our study, this time consists solely in the research and illumination of pollution with these heavy metals and waterworks of the Ibër River, as a result of the pollution caused by the industrial waste landfill located in Kelmend village. In the paper, we have attempted to show the concentration of heavy metals in sediment and water, by pointing at four sample sites of the Ibër river: in the Bosniak U1 neighborhood, then in the flow in front the U2 landfill, discharge flows from landfill U3 and a certain distance from the U4 landfill.