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Low waste technology for the removal of nitrates from water

Trus Inna, Gomelya Mukola, Halysh Vita, Tverdokhlib Mariia, Makarenko Iryna, Pylypenko Tetiana, Chuprinov Yevhen, Benatov Daniel, Zaitsev Hennadii

Archives of Environmental Protection

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2023

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Vol. 49, no 1

74--78

EN

As a rule, nitrates are present in all natural water bodies. Their increased concentrations are connected with the discharge of insufficiently treated wastewater from industrial and communal enterprises, agricultural and livestock complexes. Recent scientific publications concerning treatment methods for nitrates removal from natural water and wastewater were analyzed in order to create effective and low-waste technology for obtaining high quality water. It has been established that the ion exchange method is quite effective for removing nitrates from water. In the paper, the processes of ion exchange removal of nitrates from water on low-axis anionite in DOWEX Marathon WBA in Сl- form were investigated. During the sorption of nitrates with a concentration of 186, 205, 223 and 2200 mg/dm3, it was established that the full exchangeable dynamic capacity was 1.075, 1.103, and 1.195, 1.698 g-eq/dm3, respectively. To regenerate anionite, solutions of ammonia as well as potassium chloride, ammonium chloride and potassium carbonate were used in this work. The choice of potassium and ammonium compounds is due to the prospect of further use of regeneration solutions for the production of liquid fertilizers.

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Starch Modification to Ensure Resource Savings and Environmental Safety in the Production Cardboard from Waste Paper

Halysh Vita, Trus Inna, Tverdokhlib Mariia, Nosachova Yuliia, Krysenko Tamara, Hlushko Olena, Ploskonos Victor, Radovenchyk Vyacheslav, Gomelya Mykola

Journal of Ecological Engineering

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2022

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Vol. 23, nr 11

68--75

EN

Development of new and modification of existing chemicals, which act not only as binders, but also provide increased retention of fiber and other pulp components on the paper machine grid, accelerate pulp dehydration, and provide special properties (moisture resistance, heat resistance, improvement of other technical characteristics of paper and cardboard) of paper and cardboard, is an important and urgent task of chemical technology and ecology. This paper presents results of the corn starch modification with epoxypropyltriethanolammonium chloride, hexamethylolmelamine and hexamethylenetetramine. Modified starches provide the necessary strength indicators of cardboard from waste paper and low turbidity of wastewater. The obtained starches can be used in mills that use low-quality waste paper for the production of cardboard and paper products with the aim of saving fiber, reducing wastewater pollution and as a result reducing the negative impact on the environment.

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Purification of Mine Waters Using Lime and Aluminum Hydroxochloride

Trus Inna, Gomelya Mukola, Tverdokhlib Mariia, Halysh Vita, Radovenchyk Iaroslav, Benatov Daniel

Ecological Engineering & Environmental Technology

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2022

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Vol. 23, iss. 5

169--176

EN

Analysis of the scientific and technical literature shows that there are quite a few methods of mine water processing. Reagent methods can be considered as the most promising and economically expedient. Mine waters are characterized by a high content of hardness ions and sulfates. The concentration of sulfates varies between 5–35 mg-eq/dm3, hardness – 10–40 mg-eq/dm3. It has been established that effective purification of water from sulfates can be achieved with the use of lime and 5/6 aluminum hydroxochloride. The efficiency of the process depends on the doses and ratio of reagents. The degree of softening and purification of water from sulfates increases with an increase in the dose of aluminum coagulant within certain limits. When using 5/6 aluminum hydroxochloride, the efficiency of water purification from sulfates is quite high and small amounts of chlorides are introduced into the water with the coagulant.

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Usage of Sorbent-Catalyst to Accelerate the Oxidation of Manganese

Gomelya Mykola, Tverdokhlib Mariia, Shabliy Tetyana, Linyucheva Olga

Journal of Ecological Engineering

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2021

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Vol. 22, nr 4

232--239

EN

The processes of manganese (II) ions removal from water using sorbent catalysts and ion exchange materials modified with iron oxides were studied. It was shown that manganese ions oxidize very slowly in artesian water, even when the pH is adjusted to 9.0. Intensive aeration of solutions due to stirring also does not promote the oxidation of manganese (II) ions. The degree of manganese extraction due to oxidation is reduced from 20–30% for solutions with a concentration of manganese ions of 1 and 5 mg/dm3 to 11–15% for solutions with a concentration of 15 and 30 mg/dm3. A significant increase in the oxidation efficiency of manganese ions was achieved by using magnetite as a sorbent catalyst. The efficiency of water demanganization increases along with the intensity of water aeration when mixing solutions. It was established that strongly acid cation exchangers provide efficient extraction of manganese ions from water. At the same time, a high exchange capacity of strong acid cation exchange resin KU-2–8 in acid and salt form was noted. It was shown that the capacity of manganese ions of this cation exchange resin in the Ca2+-form is slightly lower. When using the KU-2–8 in Ca2+-form of cation exchange resin to remove manganese ions from the solution already in the first samples, the leakage of manganese ions at the level of 10 mg/dm3 and above was observed. This indicates that this form of ion exchanger is not suitable for deep purification of water from manganese (II) ions. In order to increase the efficiency of manganese ion extraction from water, increase the duration of the filter cycle, magnetite and magnetite-modified KU-2–8 cation exchange resin were used as a sorbent-catalyst. It was shown that the cation exchange resin modified with magnetite provides the removal of a significant part of manganese ions due to catalytic oxidation on magnetite. The conditions of effective manganese extraction under static and dynamic conditions are determined.

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Sorbent-Catalyst for Acceleration of The Iron Oxidation Process

Gomelya Mykola, Tverdokhlib Mariia, Shabliy Tetyana, Radovenchyk Vyacheslav, Linyucheva Olga

Journal of Ecological Engineering

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2021

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Vol. 22, nr 3

221--230

EN

In this work, the process of water deironing by using magnetite as a catalyst to accelerate the oxidation of iron ions in an aqueous medium was investigated. It was shown that the efficiency of iron ion extraction depends on the solution concentration, sorbent dose and contact time. In all cases, the use of magnetite accelerated the process of extraction of iron by more than an order of magnitude in comparison with similar experiments on the oxidation of iron without the addition of a catalyst. At the pH values greater than 6, the use of magnetite as a catalyst contributes to the deep purification of water from iron ions.