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1
Content available Synthesis and Characterization of 1-(1-chlorocyclopropyl)-2-(1,2,4-triazol-1-yl)ethan-1-one
Ji H., Niu Y., Liu D., Wang W., Dai C.
Polish Journal of Chemical Technology
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2017
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Vol. 19, nr 1
41--47
EN
A simple and efficient method to prepare 1-(1-chlorocyclopropyl)-2-(1,2,4-triazol-1-yl)ethan-1-one via nucleophilic substitution of 2-chloro-1-(1-chlorocyclopropyl)ethanone and 1,2,4-triazole is described. The title compound is the key intermediate required for the synthesis of prothioconazole, a promising agricultural fungicide. By exploring changes in the reaction time, temperature, ratio of starting reagents, acid binding agent, and the nature of phase transfer catalyst, the reaction conditions could be optimized to afford the desired N-alkylated material in near-quantitative yield. The ultimate yield of the product after recrystallization was 93%, with a purity of 99% based on its characterization by Gas Chromatography-Mass Spectrometer (GC-MS), Fourier Transform infrared spectroscopy (IR), Proton Magnetic Resonance (1H NMR), and Carbon-13 Nuclear Magnetic Resonance (13C NMR). The synthetic process is suitable for industrial application, with the advantages of high yield and facile preparation under mild operating conditions.
2
Content available Preparation of micro-encapsulated strawberry fragrance and its application in the aromatic wallpaper
Xiao Z., Zhang Y., Zhu G., Niu Y., Xue Z., Zhu J.
Polish Journal of Chemical Technology
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2017
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Vol. 19, nr 1
89--94
EN
Micro-encapsulated strawberry fragrance was successfully prepared with wall materials including maltodextrin, sodium octenylsuccinate and gum Arabic. The micro-capsule was added to wallpaper and aromatic wallpaper with strawberry characteristics was obtained. The particle distribution, surface morphology, chemical structure, thermal property and controlled release performance of micro-encapsulated fragrance and aromatic wallpaper were investigated using laser particle size analyzer, scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-TR), thermal gravity analysis (TGA) and chromatography-mass spectrometer (GC-MS). The results showed that the average diameter of micro-capsule was 2 μm and the particles mainly distributed in the tissues of wallpaper. The result of TGA showed that the micro-capsule had a good stability. Meanwhile, the aromatic wallpaper had strawberry aroma more than 3 months and took on excellent controlled release performance.
3
Content available Preparation, characterization and rheological behavior of chitosan nanocapsule emulsion encapsulated tuberose fragrance
Xiao Z., Wang E., Zhu G., Zhou R., Niu Y.
Polish Journal of Chemical Technology
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2016
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Vol. 18, nr 2
1--8
EN
In this paper, ionic gelation method was adopted to produce nanocapsules (CNs) encapsulated tuberose fragrance with chitosan (CS) and sodium tripolyphosphate (TPP) as wall materials. The effects of CS/TPP mass ratio, pH value of CS solution, molecular mass of CS and tuberose fragrance (TF) concentration on particle size and particle size distribution (PDI) of chitosan nanocapsules encapsulated tuberose fragrance (CNTs) were investigated systematically. CNTs were characterized by dynamic light scattering (DLS), scanning electron microscopy (SEM), Fourier transforms infrared spectroscopy (FTIR), X-ray diffraction (XRD), thermogravimetric analyzer (TGA) and differential scanning calorimetry (DSC). The results showed that CNTs were successfully prepared. The optimum preparation conditions were as follows: CS/TPP mass ratio 5:1, pH of CS solution 4.0, and molecular mass of CS 150 kda. CNTs emulsions were also systematically investigated by steady-state shear and oscillatory shear measurements respectively. The rheological behaviors of CNTs were obtained.
4
Content available Encapsulation of l-menthol in hydroxypropyl-β-cyclodextrin and release characteristics of the inclusion complex
Zhu G., Xiao Z., Zhu G., Zhou R., Niu Y.
Polish Journal of Chemical Technology
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2016
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Vol. 18, nr 3
110--116
EN
l-menthol has been widely used in flavour, food and pharmaceuticals. Because of its high volatility and whisker growth, l-menthol-hydroxypropyl-β-cyclodextrin inclusion complex was produced to improve shelf-life, provide protection, and enhance the stability of l-menthol. The inclusion complex was characterized by Fourier transform infrared spectroscopy, X-ray diffraction. The results show that l-menthol was successfully encapsulated in hydroxypropyl-β-cyclodextrin. l-menthol loading capacity is about 8.44%. Geometries and binding energies of l-menthol-hydroxypropyl-β-cyclodextrin inclusion complexes were investigated using molecular mechanics calculations. The shape and orientation of the most stable complex, and the minimum binding energy were determined. L-menthol release from complex was determined by thermogravimetric analysis. Two l-menthol release rate peaks were observed at 69.3 and 279.1°C. The l-menthol release reaction order, release activation energy and the preexponential factor were obtained.
5
Content available A combined method for reliability analysis of multi-state system of minor-repairable components
Qin J., Niu Y., Li Z.
Eksploatacja i Niezawodność
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2016
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Vol. 18, no. 1
80--88
EN
This paper discusses the multi-state system (MSS) consisted of multi-state components with minor failure and minor repair. In order to obtain the reliability indices of MSS, a new combined method is suggested. This method is based on the Markov stochastic process and the universal generating function (UGF) technology. The traditional idea of modeling the MSS is to use straightforward Markov process. That is not effective enough for the MSS because the model of the system is complicated usually and the state space often arouses “dimension curse” - huge numbers of the states. We suggest it should model the multi-state components and the UGF of multi-state components can be obtained firstly. Then the MSS can be decomposed into several subsystems which only contain simple series-parallel structure. According to the physical nature of the subsystems, the UGF of those subsystems can be employed recursively. Furthermore the UGF of the entire MSS will be obtained. Therefore, the reliability indices of the MSS can be evaluated easily. The suggested method simplifies greatly the complexity of calculation and is well formulized. Two numerical examples illustrate this method.
PL
W artykule omówiono system wielostanowy (multi-state system, MSS) składający się z elementów wielostanowych, które mogą ulegać drobnym uszkodzeniom i podlegają drobnym naprawom. Zaproponowano nową metodę łączoną, która pozwala wyznaczać wskaźniki niezawodności MSS. Metoda ta opiera się na procesie stochastycznym Markowa oraz technologii uniwersalnej funkcji tworzącej (universal generating function, UGF). Tradycyjnie do modelowania MSS wykorzystuje się sam proces Markowa. Metoda ta nie jest jednak wystarczająco skuteczna w przypadku MSS, ponieważ modele tego typu systemów są zazwyczaj skomplikowane, a przestrzeń stanów często prowadzi do tzw. "przekleństwa wielowymiarowości" – konieczności uwzględnienia ogromnej liczby stanów. Nasza metoda polega na modelowaniu elementów wielostanowych, dla których, w pierwszej kolejności wyznacza się UGF. Następnie MSS można rozłożyć na kilka podsystemów, które mają prostą strukturę szeregowo-równoległą. Charakter fizyczny tych podsystemów, pozwala na rekurencyjne stosowanie UGF dla tych podsystemów. Ponadto metoda umożliwia wyznaczenie UGF dla całego MSS, co pozwala na łatwą ocenę wskaźników niezawodności MSS. Proponowana metoda znacznie upraszcza obliczenia i jest dobrze sformalizowana. W pracy przedstawiono dwa przykłady numeryczne, które ilustrują omawianą metodę.
6
Content available Pyrolysis characteristics and kinetics of β-cyclodextrin and its two derivatives
Zhu G., Xiao Z., Zhou R., Niu Y.
Polish Journal of Chemical Technology
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2015
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Vol. 17, nr 4
1--4
EN
β-cyclodextrin (β-CD) and its derivatives have been widely used to prepare inclusion complexes. However, systematic research on their thermal stabilities, pyrolysis characteristics and kinetics has rarely been reported. In this paper, thermogravimetric analysis was employed to investigate β-cyclodextrin and its two derivatives, 2-Hydroxypropyl-β-cyclodextrin (HP-β-CD) and monochlorotriazinyl-β-cyclodextrin (MCT-β-CD). The pyrolysis characteristics and kinetic parameters were obtained. The results show that three stages can be distinguished during the heating process of the above three samples. The temperature of initial decomposition of HP-β-CD (309.5°C is higher than that of β-CD (297.8°C), while the temperature of initial decomposition of MCT-β-CD (231.4°C) is lower than that of β-CD. For the three cyclodextrins, the thermal stability in descending order is HP-β-CD, β-CD and MCT-HP-β-CD. The activation energy values are 350.6, 303.3 and 113.9 KJ/mol, and the pre-exponential factor values are 1.11×1031, 1.37×1026 and 1.39×1010 for β-CD, HP-β-CD and MCT-β-CD respectively.
7
Content available remote Uniform Solution to Common Algorithmic Problem by P Systems Working in the Minimally Parallel Mode
Niu Y., Venkat I., Khader A. T., Subramanian K. G.
Fundamenta Informaticae
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2015
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Vol. 136, nr 3
285--296
EN
It is known that the Common Algorithmic Problem (CAP) has the nice property that several other NP-complete problems can be reduced to it in linear time. The decision version of this problemis known to be efficiently solved by a family of recognizer P systems with activemembranes with three electrical charges working in the maximally parallel way. We here work with a variant of P systems with active membranes without polarizations and present a uniform solution to CAP in the minimally parallel mode.
8
Content available remote A Tissue P Systems Based Uniform Solution to Tripartite Matching Problem
Niu Y., Pan L., Pérez-Jiménez M.J., Font M. R.
Fundamenta Informaticae
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2011
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Vol. 109, nr 2
179-188
EN
A tissue P system with cell division is a computing model which has two basic features: intercellular communication and the ability of cell division. The ability of cell division allows us to obtain an exponential amount of cells in linear time and to design cellular solutions to computationally hard problems in polynomial time. In this work we present an efficient solution to the tripartite matching problem by a family of such devices. This solution leads to an interesting open problem whether tissue P systems with cell division and communication rules of length 2 can solve NPcomplete problems. An answer to this open problem will provide a borderline between efficiency and non-efficiency in terms of the lengths of communication rules.
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