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The Synthesis, Spectroscopic Investigation,Crystal and Molecular Structure of the [ReCl2(N2COPh)(2,3'-bpy)(PPh3)2] Complex

Michalik S., Dzięgielewski J., Kruszyński R.

Polish Journal of Chemistry

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2006

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Vol. 80, nr 5

685-691

EN

The [ReCl2(N2COPh)(2,3'-bpy)(PPh3)2] complex has been obtained in the reaction of [ReCl2(2-N2COPh-N',O)(PPh3)2] with an excess of 2,3'-bipyridyl. The [ReCl2(N2COPh)(2,3'-bpy)(PPh3)2] complex crystallizes in the triclinic space group P-1. The complex was characterized by IR, UV-VIS, and magnetical measurements. The geometries of the complex was optimized with the DFT method.

2

Spectroscopic Characterization, Crystal and Molecular Structure of [ReBr2N(PPh3)2]

Dzięgielewski J., Michalik S., Jaworska M., Kruszyński R., Kusz J.

Polish Journal of Chemistry

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2005

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Vol. 79 / nr 7

1193-1203

EN

Rhenium nitrido-complex [ReNBr2(PPh3)2] has been characterized by X-ray diffraction, IR and UV-Vis spectroscopies. The geometry optimization was carried out with the DFT method using B3LYP functional. The electronic spectrum was calculated with the TDDFT method.

3

The Syntheses, Crystal, Molecular and Electronic Structures of [ReBr3(py)3]0.42[ReBr2(NO)(py)3]0.58, trans-[ReBr4(OPPh3)2] and Orthorhombic Polymorph of mer-cis-[ReBr3(NO)(OPPh3)2]

Machura B., Dzięgielewski J., Kusz J.

Polish Journal of Chemistry

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2003

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Vol. 77 / nr 5

519-533

EN

[ReBr3(py)3]0.42[ReBr2(NO)(py)3]0.58 (1), trans-[ReBr4(OPPh3)2] (2), [ReBr(NO)(dppe)2]Br (3) and orthorhombic polymorph of mer-cis- [Re(NO)Br3(OPPh3)2] (4) complexes have been synthesized by reactions of monoclinic polymorph of mer-cis-[Re(NO)Br3(OPPh3)2] with pyridine, bis(diphenylophosphino) ethane, 2,2_-bipyridine, 1,10-phenanthroline. The NO group in 1 and 4 is coordinated in a linear way. Due to nitrosyl/bromine compositional disorder, the shortening of Re-NO distance [1.68(5) A] and the elongation of N-O bond length [1.38(10) A] are observed in1. The N-O bond length in 4 is extremely short [0.94(1) A], which results probably from steric interactions of two mutually cis OPPh3 molecules and a large discrepancy of Re-O-P angle values.

4

The Synthesis, Spectroscopic Characterization, Crystal and Molecular Structure of [ReBr3(NO)(dppe)]0.60[ReBr4(dppe)]0.40

Dzięgielewski J., Machura B., Małecki J., Bartczak T., Czurak W.

Polish Journal of Chemistry

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2000

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Vol. 74, nr 2

191-198

EN

[ReOBr3(dppe)] (where dppe denotes Ph2PCH2CH2PPh2) reacts with gaseous nitric oxide in the presence of an acces of free PPh3 to give [ReBr3(NO)(dppe)0.60[ReBr4(dppe)]0.40, characterized by X-ray crystallography, IR, UV-Vis, and magnetochemical measurements. The coplex is a paramagnetic compound with magnetic moment 2.54 MB.

5

The Crystal, Molecular and Electronic Structure od [ReBr2(NO)(CO)(PPh3)2] NO Complex

Bartczak T., Czurak W., Dzięgielewski J., Machura B., Kusz J., Warczewski J.

Polish Journal of Chemistry

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2000

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Vol. 74, nr 2

265-273

EN

A new rhenium nitrosyl complex [ReBr2(NO)(CO)(PPh3)2]*NO has been synthesized and characterized by X-ray diffraction, IR, UV-Vis and magnetochemical easurements. The Re atom is of six-coordinate distorted octahedral configuration and linear nitrosyl ligand is trans towards the bromine ligand and cis towards CO molecule.