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Magnetism and electronic structure of hexagonal 1:1:1 rare earth-based intermetallic compounds

Gondek Ł, Żukrowski J, Bałanda M, Kaczorowski D, Szytuła A

Materials Science Poland

2008

Vol. 26, No. 4

815--820

Correlations between magnetic properties and electronic structure of rare earth based intermetallics of the ZrNiAl-type crystal structure have been analysed. The analysis has been supported by results of magnetometric, neutron diffraction and photoelectron spectroscopy measurements. It has been demonstrated that structure of the valence band and crystal electric field effects are the most important factors affecting the magnetic behaviour of the discussed compounds.

Mediation of Magnetic Interactions in Prussian Blue Family

Wasiutyński T., Bałanda M., Szeglowski Z., Zieliński P. M.

Polish Journal of Chemistry

2002

Vol. 76 / nr 2-3

377-384

Results of the AC susceptibility and DC magnetization of the family ACo[Fe(CN)6] for different cations A: Li, Na, K, Rb, Cs,NH4, N(Et)4 are presented. Differences in magnetic properties are found that can be attributed to an indirect interaction mediated by the cations. Two other compounds: A2NiII[FeII(CN)6] (A = K, Na) were also studied. The strong influence on magnetic properties due to alkaline cations was again observed.