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Stabilization/Solidification of Waste Containing Heavy Metals and Hydrocarbons Using OPC and Land Trass Cement

Masrullita, Burhan R. Y. P., Trihadiningrum Y.

Journal of Ecological Engineering

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2018

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Vol. 19, nr 6

88--96

EN

The stabilization/solidification process (S/S) is one of the alternative methods of treating B3 waste, especially heavy metal. The S/S uses cement as the solidification agent. The cement will bind heavy metal pollutants in a monolithic mass with a sturdy structure, thus inhibiting its movement. The presence of hydrocarbons affects the S/S strength. Therefore, it is necessary to add pozzolan material which can absorb hydrocarbon constituting the cement blocking component of pozzolan cement, i.e. Ordinary Portland Cement (OPC) combined with trass soil. This study aims to determine the maximum content of organic materials in the form of hydrocarbons can stabilize/solidify heavy metals contained in wastes containing hydrocarbons. This research is conducted in two steps. Stage I aims to obtain the optimum composition of the mixture. On the other hand, stage II is to determine the maximum content of hydrocarbons in percent weight that can stabilize/solidify organic wastes containing heavy metals – Cu, Cr, and Pb in artificial wastes. The composition of OPC and trass soil was varied at a ratio of 100: 0, 5:25, 50:50, 25:75 and 0: 100. The hydrocarbons used in step II were paraffin, added to the optimum composition of OPC and trass soil with a proportion of 2.5%, 5%, 5% and 10%. The S/S product quality test was performed, involving: compressive strength test, Toxicity Characteristic Leaching Procedure (TCLP) and paint filter test. Strength test was conducted using a compressive strength testing apparatus Toasters Universal Testing Machine Type RAT-200, MFG No. 20380 CAP 200 tf. TCLP test under US-EPA (method 1311). The method of analysis pertaining to heavy metal concentrations involved a colorimetric method for Cr (VI), neocuproine for Cu, and dithizone for Pb. The paint test refers to the US EPA 9095B method. The results showed that the optimum composition of OPC mixture: trass soil was 50:50, which is the composition used in stage II. The results of compressive strength test were 2770 tons/m2. The TCLP test results for heavy metals Cu and Pb with hydrocarbon addition on Cu 10% and Pb 2.5% reached 0.076 and 0.076 mg/L, respectively. The result of the paint filter test indicates that there is no remaining free fluid.

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Stabilization/Solidification of Tailing on Traditional Gold Mining in Kulon Progo Using Fly Ash

Rachman R. M., Bahri A. S., Trihadiningrum Y.

Journal of Ecological Engineering

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2018

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Vol. 19, nr 3

178--184

EN

Traditional gold mining activity is one of the sources of mercury contamination. Total mercury concentration in tailing ponds in Kulon Progo ranged from 164.49 mg/kg to 383.21 mg/kg, which exceeded the quality standard values set by the government of Indonesia No. 101 of 2014, which is 75 mg/kg. One method that can be applied is stabilization/solidification (S/S). This study aims to determine the optimum composition of the tailing mixture with fly ash in S/S process. The variations of fly ash composition with tailing are 100: 0, 90: 10, 80: 20, 70: 30, 60: 40, 50: 50, 40: 60, 30: 70, 20: 80 and 10: 90. The results of the study found that the optimum composition of fly ash: tailings was 10: 90, with compression test of 74 ton/m2 and TCLP test was 0.0069 mg/L. The obtained compression test results were in accordance with US EPA Standard quality of 35 ton/m2. TCLP test results meet the standard of Indonesian Government Regulation no. 101 of 2014, amounting to 0.05 mg/L.

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Petroleum Hydrocarbon Pollution in Soil and Surface Water by Public Oil Fields in Wonocolo Sub-district, Indonesia

Sari G. L., Trihadiningrum Y., Ni'matuzahroh N.

Journal of Ecological Engineering

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2018

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Vol. 19, nr 2

184--193

EN

Public crude oil fields in Wonocolo sub-district were active from 1942 until now and have inadequately operated. The aims of this research were to measure the level of total petroleum hydrocarbon (TPH) pollution and their distribution in soil and surface water at the Wonocolo public crude oil fields. Twelve composite soil samples were collected from uncontaminated and contaminated sites of old well (OW), transportation line (T), and refinery area (R) at the depths of 0–30 cm, 30–60 cm, and 60–90 cm. The composite surface water sample was obtained from two points with different distances from the river side. TPH from soil and surface water samples were extracted using soxhlet and gravimetric method. Quantification of TPH was performed using Fourier Transform Infrared (FT-IR) Spectrometer. From the results of this study, it was concluded that soils and surface water are contaminated by TPH of 119.80–107,190 µg/g and 211,025.73 µg/L, respectively. TPH is clearly located in the upper of 0–30 cm depth at OW, T, and R sites (52,328.14–107,189.63 µg/g). These concentrations exceeded the soil quality standard of TPH and classified as category A for human hazard risk. The findings from this study show that there are considerable health risks which are potentially poisonous to humans in the local area. We recommend that remediation could be conducted using biological methods to reduce TPH pollution level.