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2 Archives of Metallurgy and Materials

2 2016

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Low temperature broad band dielectric spectroscopy of multiferroic Bi6Fe2Ti3O18 ceramics

Lisińska-Czekaj A., Rerak M., Czekaj D., Lubina M., Garbarz-Glos B., Bąk W.

Archives of Metallurgy and Materials

2016

Vol. 61, iss. 3

1447--1452

In the present research the tool of broadband dielectric spectroscopy was utilized to characterize dielectric behavior of Bi6Fe2Ti3O18is (BFTO) Aurivillius-type multiferroic ceramics. Dielectric response of BFTO ceramics was studied in the frequency domain (Δν=0.1Hz - 10MHz) within the temperature range ΔΤ=-100°C - 200°C. The Kramers-Kronig data validation test was employed to validate the impedance data measurements and it was found that the measured impedance data exhibited good quality justifying further analysis. The residuals were found to be less than 1%, whereas the "chi-square" parameter was within the range χ2~-10-7 -10-5. Experimental data were analyzed using the circle fit of simple impedance arc plotted in the complex Z”-Z` plane (Nyquist plot). The total ac conductivity of the grain boundaries was thus revealed and the activation energy of ac conductivity for the grain boundaries was calculated. It was found that activation energy of ac conductivity of grain boundaries changes from ΕA=0.20eV to ΕA=0.55eV while temperature rises from Τ=-100°C up to Τ=200°C. On the base of maxima of the impedance semicircles (ωmτm=l) the relaxation phenomena were characterized in terms of the temperature dependence of relaxation times and relevant activation energy was calculated (ΕA=0.55eV).

Influence of Processing Conditions on Crystal Structure of Bi6Fe2Ti3O18 Ceramics

Lisińska-Czekaj A., Lubina M., Czekaj D., Rerak M., Garbarz-Glos B., Bąk W.

Archives of Metallurgy and Materials

2016

Vol. 61, iss. 2A

881--886

Aim of the present research was to apply a solid state reaction route to fabricate Aurivillius-type ceramics described with the formula Bi6Fe2Ti3O18 (BFTO) and reveal the influence of processing conditions on its crystal structure. Pressureless sintering in ambient air was employed and the sintering temperatures were 850 and 1080 °C. It was found that the fabricated BFTO ceramics were multiphase ones. They consisted of two Bim+1Fem-3Ti3O3m+3 phases, namely the phase with m=5 (i.e. the stoichiometric phase) and m=4 (i.e. the phase with a reduced number of layers in the slab). Detailed X-ray diffraction patterns analysis showed that both phases adopted the same orthorhombic structure described with Fmm2 (42) space group. The ratio of weight fractions of the constituent phases (m=5): (m=4) was ~30:70.