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Bio-ketones from lignocellulosic biomass: experimental investigation on fuel properties, combustion and emissions characteristics of cyclopentanone blend with diesel in compression ignition engine

Doustdar O., Wyszynski M. L., Tsolakis A., Mahmoudi H.

Combustion Engines

2017

R. 56, nr 4

81--86

Use of alternative fuels in compression ignition engines is the topic for many studies. This paper presents the results of lubricity, calorific value, viscosity, surface tension and density of a ketone blend with diesel to use as a fuel in compression ignition engine. Analyses of fuel properties are vital due to their effect on fuel system. In addition, this study is related to the development of future biofuels and it indicates the effect of oxygen double bond in molecular structure of ketones on important fuel properties. Cyclopentanone which has cyclic molecular structure was used; it can be produced from lignocellulosic biomass through various processing ways. This ketone was blended with diesel fuel at 10% vol. Results from fuel properties tests were compared to the conventional diesel fuel. In the next step this blend was tested in a research diesel engine to analyse its combustion behaviour and emission characteristics of exhaust gases; these results were compared with ultra-low sulphur diesel fuel. Results showed that cyclopentanone, as an additive to diesel, improved surface tension and density of the fuel but in contrast had negative effect on viscosity, lubricity and calorific value of the fuel, but still in the standard range. Combustion behaviour of this fuel in the diesel engine also showed longer ignition delay of ketone blend and also that gaseous emission such as CO and THC are higher than from diesel fuel and NOx emission is less than from conventional diesel fuel combustion.

Performance of a drop-in biofuel emulsion on a single-cylinder research diesel engine

Bogarra-Macias M., Doustdar O., Fayad M. A., Wyszyński M. L., Tsolakis A., Ding P., Pacek A., Martin P., Overend R., O'Leary S.

Combustion Engines

2016

R. 55, nr 3

9--16

Current targets in reducing CO2 and other greenhouse gases as well as fossil fuel depletion have promoted the research for alternatives to petroleum-based fuels. Pyrolysis oil (PO) from biomass and waste oil is seen as a method to reduce life-cycle CO2, broaden the energy mix and increase the use of renewable fuels. The abundancy and low prices of feedstock have attracted the attention of biomass pyrolysis in order to obtain energy-dense products. Research has been carried out in optimising the pyrolysis process, finding efficient ways to convert the waste to energy. However, the pyrolysis products have a high content in water, high viscosity and high corrosiveness which makes them unsuitable for engine combustion. Upgrading processes such as gasification, trans-esterification or hydro-deoxynegation are then needed. These processes are normally costly and require high energy input. Thus, emulsification in fossil fuels or alcohols is being used as an alternative. In this research work, the feasibility of using PO-diesel emulsion in a single-cylinder diesel engine has been investigated. In-cylinder pressure, regulated gaseous emissions, particulate matter, fuel consumption and lubricity analysis reported. The tests were carried out of a stable non-corrosive wood pyrolysis product produced by Future Blends Ltd of Milton Park, Oxfordshire, UK. The product is trademarked by FBL, and is a stabilized fraction of raw pyrolysis oil produced in a process for which the patent is pending. The results show an increase in gaseous emissions, fuel consumption and a reduction in soot. The combustion was delayed with the emulsified fuel and a high variability was observed during engine operation.