Velocity and absorption of ultrasonic waves in aqueuos solutions of a-cyclodextrin containing amphiphil substances with different ``heads" and identic ``tails" were carried out. As a result of the mutual interactions between a-cyclodextrin and the amphiphil substance the low frequency ultrasonic relaxation process has been established. Thermodynamic and kinetic parameters related to this process have been calculated. Obtained results have been discussed considering molecular structure of the amphiphil substances.
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In second part of this work, velocity and absorption measurements of ultrasonic waves in aqueous solutions of ß-cyclodextrin containing different sodium alkyl sulfates are reported. One or two relaxation processes for these solutions have been established. Thermodynamic and kinetic parameters related to these processes have been calculated. The results have been compared with those obtained for solutions of ?-cyclodextrin and presented in Part 1 of this paper. Explanation of the origins of these processes has been proposed.
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In this part, the velocity and absorption measurements of ultrasonic waves in aqueous solutions of [alpha]-cyclodextrin containing different sodium alkyl sulfates are reported. One or two relaxation processes for these solutions have been established. Thermodynamic and kinetic parameters related to these processes have been calculated. In the second part, experimental results for ß-cyclodextrin will be reported and compared with those presented here.
In this paper the results of ultrasonic longitudinal and shear measurements in vegetable oils are presented and discussed. The run of the ultrasonic attenuation suggests a relaxation process at frequencies below 0.5MHz. Another one is suggested at low temperature in the vicinity of 1Hz.
Measurements of the absorption coefficient, alfa/f2, of aqueous solutions of ?-cyclodextrin with alkylpyridinium bromides CnH2n+1C5H4NBr or alkyltrimethylammonium bromides CnH2n+1N(CH3)3Br (n=8, 10, 12), were carried out at 15, 25, 35 and 45oC in the concentration range 0.01M to 0.04M and frequency range 1MHz to 150MHz. The occurrence of two ultrasonic relaxation processes has been noted. The obtained results have been compared with data published previously for sodium alkyl sulfates.
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