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EN
In order to further understand the detonation characteristics of annular booster pellets, the energy convergence effect from the detonation wave on the central axis was investigated by using the segmentation and lower end surface output. The result shows that in the whole explosion process, the power exportation capability (N) of the converging energy flow into the central axis increases, then decreases, and then increases and finally decreases. When the collision incidence angle of the detonation waves (or shock waves) reaches a critical value (φcr), Mach reflection occurs at the position on the central axis from the upper end face, as expressed by the formula hc = Lg·tanφcr at time t. The pressure at the collision point rises abruptly to the maximum pressure with a maximum of the power capacity. The segmentation and lower end face output opens up a new test method for the optimal design of the special-shaped booster explosive.
EN
When mining coal from the working face, the main roof withstands the overlying strata. The main roof’s first weighting and periodic weighting may cause accidents, such as crushing the working face hydraulic supports. A mechanical model of the main roof was constructed, and the contributing factors of first and periodic weights on the main roof were examined in order to prevent such accidents. The thickness of the main roof was found as the most contributory factor to the main roof’s stability. Therefore, a new directional roof crack (DRC) technique is proposed, which produces directional cracks in the main roof through directional blasting and makes part of it collapse in advance so as to reduce the thickness and relieve the first and periodic weighting. To verify the effectiveness of DRC, the mechanism of DRC was analysed. A mechanical model of the hydraulic support was constructed, and the DRC techniques were tested on-site. Field experiments with a complete set of monitoring schemes showed that, with DRC technology, the roof periodic weighting interval decreased by 35.36%, and the hydraulic support pressure decreased by 17.56%. The theoretical analysis was consistent with the measured results. Therefore, the DRC technology is feasible and effective to ensure mining safety at the working face.
EN
Soil parameters along the heading direction are subjected to spatial variability during shield construction, so grouting pressure requires constant adjustment to ensure ground stress sta- bility. This causes grouting pressure to fluctuate around the design pressure/curve. There- fore, the influence of the grouting pressure volatility on the adjacent loaded-pile foundation should be considered in shield tunneling. In this study, a refined numerical simulation of the shield construction process is conducted using the Fast Lagrangian Analysis of Continua in Three Dimensions (FLAC3D) software. A total of 300 groups of grouting pressure pa- rameters with a skewed normal distribution are input into the numerical model. Then, the influence of the construction parameter uncertainty on the adjacent loaded-pile foundation is analyzed. Finally, the back analysis method is conducted based on the monitored data to evaluate how the construction process affects the pile foundation. The calculation results are compared with those of the traditional finite element method. The results indicate that in the tunneling process, the grouting pressure fluctuation greatly affects the additional bend- ing moment of the adjacent pile foundation. Under the influence of the grouting pressure, the additional axial force and additional bending moment of the pile foundation also follow the skewed normal distribution. The back analysis results of the pile foundation are greater than those of the typical numerical method by about 60% 100%, that is using the back analysis calculation results to evaluate the pile foundation additional response can reduce the risk.
EN
Abstract: The polymorphic transition of 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazatetracyclo[5.5.0.05,9.03,11]dodecane (CL-20) is influenced by the materials and conditions used in the preparation of propellants, and limits the application of ε-CL-20 in solid propellants. In the present work, the effect of dinitroxydiethylnitramine (DINA) on the polymorphic transition of ε-CL-20 in CMDB propellants was investigated by Raman spectroscopy and the Calvet microcalorimeter method. The performance of propellants with CL-20 as affected by DINA was studied by the theoretical prediction of their energetic parameters, stability, combustion, and mechanical tests, respectively. The results showed that the polymorphic transition temperature of ε-CL-20 to α-CL-20 can be reduced to 75 °C by DINA. Expansion of the crystal volume during the process of the ε-CL-20 to α-CL-20 transition will produce obvious cracks in the surface of the crystals. NC/NG can inhibit the effect of DINA on the polymorphic transition of ε-CL-20. The theoretically predicted results indicated that adding DINA will not lower the energy level of CMDB propellants containing CL-20. The DSC and VST results showed that CL-20 has good compatibility and thermal stability with DINA. The burning rate tests revealed that adding DINA decreases the burning rates of CMDB propellants containing CL-20. Mechanical property testing showed that adding DINA can clearly improve the mechanical properties of CMDB propellants containing CL-20. The results of these investigations suggested that DINA has no effect on the crystalline stability of ε-CL-20 in the solventless extrusion process, which contributes to a significant understanding of practical applications and provides guidance for applied research on the use of CL-20 in propellants.
EN
A green procedure for the one-pot three-component synthesis of 1-amidoalkyl-2-naphthol and 3-amino-1-phenyl-1H benzo[f]chromene-2-carbonitrile derivatives from the reaction of 2-naphtol, aldehydes, and malononitrile/acetamide in the presence of a catalytic amount of Fe3O4@enamine-B(OSO3H)2 as an efficient and novel heterogeneous magnetic nanostructure catalyst is described. The catalyst was characterized using Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), vibrating sample magnetometry (VSM), energy dispersive X-ray spectroscopy (EDX), and X-ray diffraction (XRD). These strategies possess some merits such as simple work-up method, easy preparation of the catalyst, short reaction times, good-to-high yields, and non-use of hazardous solvents during all steps of the reactions. Moreover, due to the magnetic nature of the catalyst, it was readily recovered by magnetic decantation and can be recycled at least six runs with no considerable decrease in catalytic activity.
EN
The precise location of the needle tip is critical in robot-assisted needle-based percutaneous interventions. An automatic needle tip measuring system based on binocular vision technology with the advantages of non-contact, excellent accuracy and high stability is designed and evaluated. First the measurement requirements of the prostate intervention robot are introduced. A laser interferometer is used as the reference for measuring the position of the needle tip whose relative position variation is described as the needle tip distance in the time domain. The parameters of the binocular cameras are obtained by Zhang’s calibration method. Then a robust needle tip extraction algorithm is specially designed to detect the pixel coordinates of the needle tip without installing the marked points. Once the binocular cameras have completed the stereo matching, the 3D coordinates of the needle tip are estimated. The measurement capability analysis (MCA) is used to evaluate the performance of the proposed system. The accuracy of the system can be controlled within 0.3621 mm. The agreement analysis is conducted by the Bland-Altman analysis, and the Pearson correlation coefficient is 0.999847. The P/T ratio value is 16.42% in the repeatability analysis. The results indicate that the accuracy and stability of the binocular vision needle tip measuring system are adequate to meet the requirement for the needle tip measurement in percutaneous interventions.
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