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The Influence of Solvent on the Reaction Between Iron (II), (III) and tert-Butyl Hydroperoxide-Electrochemical Catalytic Processes of Reductants

Pacześniak T., Sobkowiak A.

Polish Journal of Chemistry

2004

Vol. 78 / nr 9

1611-1618

It has been found that tert-butyl hydroperoxide is analogous to hydrogen peroxide with respect to their reactivity towards iron(II) and iron(III). In water iron(II) is oxidized by tert-butyl hydroperoxide, whereas in acetonitrile iron(III) is reduced by tert-butyl hydroperoxide. The last reaction when performed by cyclic-voltammetry is an example of electrochemical catalytic processes of reductants.