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Hydrome-metallurgical waste management: Turning metal-enriched waste into valuable resources

Brožová Silvie, Brož Jiří, Ingaldi Manuela

Zeszyty Naukowe Akademii Morskiej w Szczecinie

2023

nr 75 (147)

107-113

The convergence of hydrometallurgical waste management and the principles of the circular economy holds immense potential for addressing the challenges posed by metal-enriched waste. By turning waste into valuable resources through efficient metal extraction, this approach not only aligns with sustainable development goals but also contributes to the conservation of resources, reduction of waste, and the promotion of economic and environmental well-being. This article deals with the further possibilities of processing metal-bearing wastes in the form of steel drifts via hydrometallurgy. The main part of this research focuses on the development of suitable technology for the leaching of steel flakes to obtain selected non-ferrous metals, mainly zinc and lead, for economic and environmental reasons. Laboratory experiments are carried out to verify a suitable leaching agent in the form of high-temperature acid leaching, neutralizing leaching, and magnetic separation verified in lead seals. From the results of the experiments, a suitable technology for processing steel fumes is proposed.

Innovative hydrometallurgy for galvanic sludge sustainable recovery

Brožová Silvie, Drápala Jaromír, Brož Jiří, Macháčková Adéla

System Safety : Human - Technical Facility - Environment

2023

Vol. 5, iss. 1

46--56

The manuscript explores the feasibility of recovering zinc and iron from waste galvanic sludge generated during galvanic plating processes. Galvanic sludge, characterized by elevated concentrations of heavy metals, represents a suitable candidate for hydrometallurgical recycling. The primary objective of the experimental and practical phases was to extract zinc and iron through the leaching of galvanic sludge. Leaching procedures were conducted using sulfuric acid at varying temperatures and time durations, augmented by the introduction of oxidizing agents such as hydrogen peroxide or ozone. Subsequent separation of the leach and filtrate was achieved through filtration. The leachate underwent additional processing involving the precipitation of iron and other metals, employing diverse agents. Following further filtration, electrolysis was employed to attain pure zinc on the cathode, utilizing an electrical voltage of approximately 3 V. Comprehensive chemical analyses were conducted on all intermediate products, including the leachate, leach liquor, filtrate, solid precipitate, and the separated metal on the cathode. The outcomes of these analyses are meticulously presented in tables and graphs.