Electrochemical approaches are generally suitable for the low-temperature CO2- conversion to carbon-based simple organic fuels or utility chemicals. Different concepts of utilization, including nanostructuring, hybridization, admixing, preconditioning, modification or functionalization of various catalytic systems for catalytic electroreduction of CO2 are elucidated, as well as important strategies to enhance the systems’ overall activity are discussed. Significance of experimental conditions, including temperature, pressure or concentration of CO2, a choice of electrolyte, its acidity, and presence of certain cations and anions are also addressed.
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