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A novel DOPO-g-KH550 modification wood fibers and its effects on the properties of composite phenolic foams

Ma Y., Geng X., Zhang X., Wang C., Chu F.

Polish Journal of Chemical Technology

2018

Vol. 20, nr 2

47--53

A novel 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) graft γ-amino propyl triethoxy silane (KH550) was synthesized and introduced on the surface of wood fi ber. Finally DOPO-g-KH550 treated wood fi ber (DKTWF) was used to prepare DKTWF composite phenolic foams (DKTWFCPF). The structures of DOPO-g- KH550 was acknowledged by Fourier transform infrared (FT-IR) and nuclear magnetic resonance (1 H-NMR). The structures of DKTWF were confirmed by FT-IR. Compared with wood fi ber, the diffraction peaks’ position was basically unchanged, but the crystallinity was slightly increased and thermal stability were dramatically improved, T5% and Tmax increased by 21.9° and 36.1° respectively. But the char yield (800°) was slightly reduced. With the dosage of DKWF, there were different degrees of improvement including the mechanical properties, flame retardancy and microstructure of DKTWFCPF. Comprehensive analysis, the interfacial compatibility was signifi cantly improved between DKTWF and phenolic resin, and the suitable content of DKTWF was 4%.

The structure and properties of eucalyptus fiber/phenolic foam composites under N-β(aminoethyl)-γ-aminopropyl trimethoxy silane pretreatments

Ma Y., Wang C., Chu F.

Polish Journal of Chemical Technology

2017

Vol. 19, nr 4

116--121

Eucalyptus fibers were modified with N-β(aminoethyl)-γ-aminopropyl trimethoxy silane to research the fiber surface’s changes and the influence of the treatment on the mechanical properties, flame resistance, thermal conductivity and microstructure of eucalyptus fiber composite phenolic foams (EFCPFs). The results showed that the partial of hemicelluloses, waxes, lignin and impurities from the fiber surface were dissolved and removed. Compared with untreated EFCPFs, the mechanical properties of treated EFCPFs were increased dramatically; The size of cells was smaller and the distribution was more uniform; The thermal conductivities were basically reduced; Especially the ratio of mass loss decreased obviously. However limited oxygen indexs (LOIs) reduced. And the mechanical properties and LOIs of EFCPFs were basically decreased with the increase of eucalyptus fibers. By comprehensive analysis, the results showed that the interfacial compatibility has been significantly improved between eucalyptus fibers and phenolic resin. And the suitable dosage of eucalyptus fibers was about 5%.