The isothermal section of the phase diagram of the Zr-Cu-Sn system has been constructed at 770 and 670 K. Two new ternary compounds were obtained and their crystal structure was determined. The ZrCuSn stannide crystallized with the TiNiSi structure type (space group Pnma, a=6.6279(1) A, b=4.3679(9) A, c=7.6791(2) A), the ZrCuSn2 structure belongs to the HfCuSi2 structure type (space group P4/nmm, a= 4.1350(7) A, c=9.225(3) A). Electrical resistivity and magnetic susceptibility of these compounds have been measured.
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