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1

Kinetic research of quinoline, pyridine and phenol adsorption on modified coking coal

Sun X., Xu H., Wang J., Ning K., Huang G., Yu Y., Ma L.

Physicochemical Problems of Mineral Processing

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2018

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Vol. 54, iss. 3

965--974

EN

Adsorption is widely used in wastewater treatment. In this work, the removal of quinoline, pyridine and phenol from coking wastewater by using modified coking coal, which was treated by four different modification methods i.e. acidification sodium hydroxide (5 mol/dm3), hydrochloric acid (5 mol/dm3) and acetic acid (5 mol/dm3) and low-temperature (105 oC) oxidation, was investigated. The modified coal was characterized by the surface area analysis, SEM, total acidity and basicity and FT-IR. The results showed that the surface area from high to low follows the order: modification with acetic acid, modification with hydrochloric acid, raw coal, modification with sodium hydroxide and modification with low-temperature. Experimental data were fitted to pseudo-first-order, pseudo-second-order and intra-particle diffusion. The adsorption of all followed pseudo-second-order kinetics. The result showed that the removal efficiency of coal modified by hydrochloric acid and acetic acid are higher than raw coal, while modified by sodium hydroxide and low-temperature are lower than raw coal., The coal modified by hydroxide acid had the best adsorption capacity.

2

Effect of gas holdup on the efficiency of cyclonic-static microbubble flotation column for oily wastewater treatment

Ning K., Huang G., Xu H., Wu L., Li X., Wang Y.

Environment Protection Engineering

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2018

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Vol. 44, nr 2

5--17

EN

A cyclonic-static microbubble flotation column of a novel construction was used in oil-water separation fields and has high efficiency for oil-water separation. The gas holdup is a key parameter for the evaluation of the performance of a flotation column. The gas holdup, closely related to the bubble size, bubble velocity and superficial gas velocity, is one of the most important parameters characterizing the hydrodynamics of a bubble column. The effect of gas holdup in a cyclonic-static microbubble flotation column was investigated. In addition, several operating parameters such as the circulating pressure, superficial gas velocity, and frother consumption were also investigated. The gas holdup was positively correlated to the superficial gas velocity. The gas holdup of clean water and oil wastewater increased along with the increase of the frother consumption. The separation mechanism of cyclonic-static microbubble flotation column was analyzed.

3

Isolation of quinolone alkaloids from Tetradium ruticarpum via preparative high-speed counter-current chromatography and evaluation of their binding affinities for bovine serum albumin

Zou H., Guo G., Wang M., Huang G.

Acta Chromatographica

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2018

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Vol. 30, no. 2

73--80

EN

By application of preparative high-speed counter-current chromatography (HSCCC) to the crude quinolone alkaloids (1.1 g) from the fruit of Tetradium ruticarpum, 1-methyl-2((6Z,9Z)-pentadecadienyl)-4(1H)-quinolone (1, 8.4 mg), dihydroevocarpine (2, 27.0 mg), and 1-methyl-2-pentadecyl-4(1H)-quinolone (3, 18.8 mg) were isolated in one step with sufficient purity using the solvent system composed of hexane–ethyl acetate–methanol–water (Hex–EtOAc–MeOH–H2O, 5:2:5:3). Further purification of the subfraction was performed by amending the solvent composition and achieved another three quinolone alkaloids, i.e., 1-methyl-2-undecylquinolin-4(1H)-one (4, 13.7 mg), (Z)-1-methyl-2-(tridec-5-en-1-yl) quinolin-4(1H)-one (5, 14.0 mg) from subfraction FR3-A3-85 using Hex–EtOAc–MeOH–H2O (5:3.5:8.75:8.25), and 1-methyl-2-nonylquinolin-4(1H)-one (6, 15.1 mg) from subfraction FR3-A3-36 using Hex–EtOAc–MeOH–H2O (5:3.8:5:4.8). The relationship between the structure of the six alkaloids and their affinities for bovine serum albumin (BSA) was investigated using fluorescence titration analysis. The length and the presence of double bond of the side chain affected their binding process with BSA. The binding behavior might influence their other biological activities.

4

Determination of the aglycon moieties of glycosidically bound compounds in Flos Chrysanthemi by GC × GC–TOFMS

Zhou Y., Huang G., Li X., Chen F., Liu H., Yang Y., Fan Z., Jiang J., Yang J.

Acta Chromatographica

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2018

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Vol. 30, no. 3

195--199

EN

A credible method for determination of the aglycon moieties of glycosidically bound aroma compounds in Flos Chrysanthemi by comprehensive two-dimensional gas chromatography–time-of-flight mass spectrometry (GC × GC–TOFMS) has been proposed. The aglycon moieties of glycosidically bound aroma compounds were isolated using methyl-tert-butyl ether (MTBE) extraction following enzymatic hydrolysis. The GC × GC–TOFMS analysis was performed to comprehensively identify different forms of the released aroma components in Flos Chrysanthemi. The result shows that the limit of detection of the released aglycon moieties ranged from 0.3 to 3.1 ng/mL, the recovery of the released 1-octanol was better than 98.3%, and the intra-day and inter-day precisions of this method were 0.2 to 8.9% and 1.3 to 9.1%, respectively. The proposed method was applied to the analysis of four types of Flos Chrysanthemi (Chuju, Boju, Hangju, and Gongju). A total of 60 aglycon moieties of interest were identified in the four types of Flos Chrysanthemi. These aglycones mainly consisted of aliphatic, aromatic, monoterpene, C13-norisoprenoids, and miscellaneous compounds.

5

Experimental study on fatigue damage of train K6 spring

Huang H., Ji S., Huang G., Qin X., Shui G.

Przegląd Elektrotechniczny

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2013

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R. 89, nr 3b

131--133

EN

Springs’ fatigue life and damage are key evaluation parameters for railway train bogies. Fatigue experiment on K6 bogie spring is carried out by digital display hydraulic pulse fatigue test device. Spring fatigue life is estimated by using nominal stress method. Based on the technology of ultrasound nondestructive test device, the relationship between accumulation of internal fatigue damage and cycle loading times is obtained. The results indicate that same batches of K6 springs have high reliability; spring material internal fatigue damage increases as cycle loading times.

PL

W artykule przedstawiono wyniki badań dotyczących zmęczenia sprężyn w podwoziach wagonowych. Analizie, przy pomocy hydraulicznego urządzenia testującego poddano sprężynę wagonową typu K6. Korzystając z badań ultradźwiękowych określono związek między tworzeniem się skupisk uszkodzeń wewnętrznych a cyklicznym obciążaniem.