Wyniki wyszukiwania - BazTech

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The Effects of Epoxidized Acrylated Castor Oil (EACO) on Soft Poly (vinyl chloride) Films as a Main Plasticizer

Song F., Xia H., Jia P., Zhang M., Hu L., Zhou Y.

Polish Journal of Chemical Technology

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2018

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Vol. 20, nr 4

13--19

EN

In this work, an environmentally friendly type plasticizer was introduced. The synthesis consisted of two steps. In the first step, castor oil (CO) was acrylated and then the acrylated castor oil (ACO) was epoxidized with the presence of formic acid and hydrogen peroxide in the second step. The epoxidized acrylated castor oil (EACO) was characterized by FTIR and 1H-NMR techniques. The EACO was used as a main plasticizer to obtain plasticized PVC materials and compared with DOP. The results showed that EACO improved polyvinyl-chloride (PVC) plasticization performance and reduced Tg from 81.06°C to 1.40°C. Plasticized PVC materials with EACO showed similar mechanical properties and better thermal stability than DOP. EACO had better volatility stabilities, migration and solvent extraction in PVC than DOP. EACO can be used to replace DOP to prepare soft films.

2

Self-Plasticization of PVC via click reaction of a monooctyl phthalate derivative

Jia P., Wang R., Hu L., Zhang M., Zhou Y.

Polish Journal of Chemical Technology

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2017

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Vol. 19, nr 3

16--19

EN

Modified PVC (M-PVC) material with suppressed migration and low glass transition temperature was prepared via click reaction of a monooctyl phthalate derivative. Chemical structure and composition of M-PVC were characterized by FT-IR, 1H NMR and element analysis. Thermal stability, glass transition temperature and migration stability of M-PVC were studied with TGA, DSC and migration tests, respectively. The study showed that M-PVC exhibited poor thermal stability, and low glass transition temperature of 66.0°C. No migration was found in distilled water, 10% (v/v) ethanol, 30% (w/v)acetic acid and petroleum ether. The PVC material is expected to preparing PVC products in the areas with high migration resistance requirement.

3

A novel biobased polyester plasticizer prepared from palm oil and its plasticizing effect on poly (vinyl chloride)

Jia P., Zhang M., Hu L., Zhou Y.

Polish Journal of Chemical Technology

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2016

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Vol. 18, nr 1

9--14

EN

In this study, palm oil was the first time to convert into a novel polyester plasticizer for polyvinyl chloride (PVC). In the first stage, palm oil was converted into palm oil monoglyceride (POM) by alcoholysis with glycerol. Next, a novel palm oil monoglycerides based polyester plasticizer (POMP) was synthesized from POM and maleic anhydride through esterification and condensation reaction. The structure of POMP was characterized with FTIR, 1H NMR and GPC. Then PVC blends were prepared using POMP as a plasticizer, melting behavior, thermal property, compatibility, mechanical properties and mechanism of plasticization of PVC blends were systematically studied. Melting behavior indicated that POMP could decrease the torque and the melt viscosity of PVC blends that was conducive to process. With the content of POMP increasing from 5 g to 15 g in PVC blends, the plasticized PVC blends demonstrated better compatibility, the degradation temperature (Td) increased from 252.6°C to 257.0°C, the glass transition temperature (Tg) decreased from 55°C to 49.5°C. Plasticization was put into effect by interaction of the electron cloud between the PVC chain and POMP molecule. This study may lead to the development of new type of PVC plasticizer based on vegetable oil.

4

The plasticizing effect of properties of manganous chloride and glycerin on poly(vinyl alcohol)

Jia P., Zhang M., Bo C., Hu L., Zhou Y.

Polish Journal of Chemical Technology

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2015

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Vol. 17, nr 2

29--33

EN

Poly(vinyl alcohol) films were prepared with manganous chloride (MnCl2 · 4H2O) and glycerin as complex plasticizer. The micro morphology of pure PVA film and complex plasticizer plasticized PVA films was observed by scanning electron microscope (SEM). The interaction between complex plasticizer and PVA molecules was investigated by Fourier transform infrared spectroscopy (FT-IR). The influence of complex plasticizer on crystalline, thermal and mechanical properties of PVA films was studied by X-ray diffraction (XRD), differential scanning calorimetry (DSC), thermogravimetric analysis (TG), and tensile testing, respectively. The results showed that the complex plasticizer of MnCl2 · 4H2O/glycerin could interacted with PVA molecular and then effectively destroy the crystals of PVA. PVA films plasticized with complex plasticizer of MnCl2 · 4H2O/glycerin became soft and ductile, with lower tensile strength and higher elongation at break compared with PVA films. This is an important cause of plasticization of the complex plasticizer of MnCl2 · 4H2O/glycerin on PVA films.

5

The fabrication and optical detection of a vertical structure organic thin film transistor

Zhang H., Wang D., Jia P.

Opto-Electronics Review

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2014

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Vol. 22, No. 1

41-44

EN

Using vacuum evaporation and sputtering process, we prepared a photoelectric transistor with the vertical structure of Cu/copper phthalocyanine (CuPc)/Al/copper phthalocyanine (CuPc)/ITO. The material of CuPc semiconductor has good photosensitive properties. Excitons will be generated after the optical signal irradiation in semiconductor material, and then transformed into photocurrent under the built-in electric field formed by the Schottky contact, as the organic transistor drive current makes the output current enlarged. The results show that the I–V characteristics of transistor are unsaturated. When device was irradiated by full band (white) light, its working current significantly increased. In full band white light, when Vec = 3 V, the ratio of light and no light current was ranged for 2.9–6.4 times. Device in the absence of light current amplification coefficient is 16.5, and white light amplification coefficient is 98.65.