Inorganic polymeric ferric chloride (POFC) coagulant with proposed structure of Fen (Cl2.2OH0.8)n is synthesized using waste materials and characterized by XRD. In the current work scrutinized efficiency of POFC for paper mill wastewater (PMW) treatment using response surface methodology (RSM) with central Composite Design (CCD) modeling. Different factors; dose, rapid mixing speed, and rapid mixing time are used for optimize the coagulation process using POFC for treating PMW. The turbidity and chemical oxygen demand (COD) removals are the indicators for assessing POFC efficiency. The obtained result for XRD confirms the production of new material of inorganic polymeric coagulants. Based on RSM modelling, there is a high correlation between the experimental and predicated removals of turbidity and COD. Subsequently, the model is significantly applied for predicating COD and turbidity removals at different operation condition. Conclusively, the obtained results proposed for practical application of POFC coagulant for treatment of paper mill wastewater for COD and turbidity elimination. Furthermore, the applied RSM with CCD is talented model for optimizing treatment of PMW.
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