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1
Content available Method of utilization of the spent vanadium catalyst
Mazurek K., Grzesiak P., Drużyński S., Kiełkowska U., Wróbel A., Szalla A.
Polish Journal of Chemical Technology
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2018
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Vol. 20, nr 3
1--7
EN
A spent vanadium catalyst, from the plant of metallurgical type, was leached in a potassium hydroxide solution to recover vanadium. The effect of time, temperature, concentration of basic, catalyst particle size and phase ratio was studied. The results showed that for a 160–750 μm catalyst leached for 4 h at 313.15 K in the presence of 10% potassium hydroxide solution at a liquid: solid ratio of 20:1, the extent of leaching of V was about 87%. Additionally, separation of vanadium from such a solution was investigated by the ion exchange method. Two types of polymer strongly basic ion exchangers were used. The ion exchange tests indicate that vanadium were loaded from the post-leaching solution with high efficiency. On this basis a flowsheet for the proposed process of a complex utilization of the spent vanadium catalyst is presented.
2
Content available remote Strącanie węglanu wapnia z płynu podestylacyjnego i roztworu wodorowęglanu sodu z metody Solvaya w obecności wersenianu disodu
Kiełkowska U., Kuchnicki P., Drużyński S.
Przemysł Chemiczny
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2016
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T. 95, nr 9
1705--1708
PL
Przedstawiono wyniki badań otrzymywania węglanu wapnia z płynu podestylacyjnego DS i nasyconego roztworu wodorowęglanu sodu z metody Solvaya w obecności wersenianu disodu. Badania prowadzono w temp. 20, 50 i 90°C. Roztwory dozowano w stosunku stechiometrycznym, stosując szybkości dozowania 23,6 oraz 95 cm3/min. Stosowano wersenian disodu o stężeniu 1 i 10 g/dm3 płynu DS. Dla otrzymanych prób CaCO3 oznaczano gęstość nasypową i utrząsową, chłonność wody, oleju parafinowego i ftalanu dibutylu, oraz formę krystalograficzną otrzymanych kryształów.
EN
CaCO3 was pptd. from the waste distn. liq. from Solvay process by addn. of satd. soln. of NaHCO3 in a lab. reactor at 20–90°C and varying dosing rate in presence of Na2 versenate and studied for bulk and packing d., cryst. structure and H2O, paraffinic oil and Bu2 phthalate absorption capacity. The addn. of Na2 versenate at 90°C resulted in an increase in the d. of CaCO3 crystals. At 90°C, the calcite and aragonite crystals were formed. At lower temps., formation of calcite crystals was also obsd.
3
Content available The Use of Ion Exchange in the Recovery of Vanadium from the Mass of a Spent Catalyst Used in the Oxidation of SO2 to SO3
Drużyński S., Mazurek K., Białowicz K.
Polish Journal of Chemical Technology
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2014
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Vol. 16, nr 2
69--73
EN
In the studies on the recovery of vanadium from vanadium catalyst extracts, three types of polymer strongly acidic ion exchangers were used. The ion exchange resins differed in terms of granularity and their ion exchange capacity. As a result, breakthrough curves were made for three main components of the test extract, i.e.: ions of vanadium, iron and potassium. On this basis the optimum conditions for the removal of iron ions from the solution were defined and the technological concept of the process in the semi-technical scale was proposed.
4
Content available Leaching of vanadium(V) from the mixture after potassium metavanadate synthesis based on KCl and spent vanadium catalyst
Kiełkowska U., Białowicz K., Drużyński S.
Polish Journal of Chemical Technology
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2013
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Vol. 15, nr 4
33-35
EN
The results of the leaching of vanadium(V) from the mixture after potassium metavanadate synthesis from KCl and spent vanadium catalyst in the presence of steam were presented. Spent vanadium catalyst was obtained from the waste storage of a chemical plant producing sulfuric acid(VI) by the contact method. The reaction mixture was leached using different solutions: 1 M Na2CO3, 20% CO(NH2)2, 15% NaOH, 15% KOH, 2 M H2SO4. The effect of time and temperature was studied. The results showed that for reaction mixture leached for 4 h at 303 K in the presence of 15% sodium hydroxide solution at a liquid:solid ratio of 10:1, the extent of leaching of vanadium(V) was 95.43%.
5
Content available Utilization of the post – filtration lye from the soda-chlorine-saltpetre method of soda production
Drużyński S., Trypuć M., Kiełkowska U., Mazurek K.
Polish Journal of Chemical Technology
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2011
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Vol. 13, nr 4
53-56
EN
The optimal conditions were determined for the precipitation of ammonium metavanadate from the solutions of ammonium nitrate with the use of sodium metavanadate. The experiments were performed with the molar ratio of salts NH4NO3:NaVO3 1.5:1 at temperatures 293, 303, 313 and 323 K. Based on the obtained results, the optimal time of the process was determined as 5 h at 293–303K. Under these conditions, the achieved yield of the precipitation process was ~98.7%, while the contents of the vanadium salts in the post – filtration solution was ~0.02%.
6
Content available remote Optymalne parametry precypitacji metawanadanu amonu z ługu pofiltracyjnego pochodzącego z otrzymywania sody z azotanu sodu
Trypuć M., Drużyński S.
Przemysł Chemiczny
|
2009
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T. 88, nr 6
722-727
7
Content available The influence of leaching solution pH and addition of peroxide hydrogen on the recovery of some components from the used vanadium catalyst with urea solutions
Mazurek K., Trypuć M., Białowicz K., Drużyński S.
Polish Journal of Chemical Technology
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2008
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Vol. 10, nr 4
34-36
EN
The research was conducted to determine the influence of the pH of the leaching solutions and hydrogen peroxide addition on the efficiency of the recovery of vanadium, potassium and iron compounds from the used vanadium catalyst from the node of oxidation of sulfur dioxide to sulfur trioxide.
8
Content available Plotting of the solubility isotherm for the NH4NO3 + NaVO3 + H2O system
Trypuć M., Drużyński S., Mazurek K.
Polish Journal of Chemical Technology
|
2008
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Vol. 10, nr 4
11-14
EN
The equilibrium research was performed for the NH4NO3 + NaVO3 + NH4VO3 + NaNO3 + H2O system at 293 and 303 K. The location of the P1 and P2 triple points was determined on the equilibrium plots with the planar projection according to Jänecke method. The maximum yield of the conversion of ammonium nitrate(V) to ammonium vanadate(V) was calculated at P1 points. The results constitute the basis to design further equilibrium experiments aimed to precisely determine the lines separating the areas of the co-crystallization of salts in the investigated system on the equilibrium plots in the oblique projection on a plane according to Jänecke method.
9
Content available Utilization of used contact masses from the oxidation state of sulfur(IV) oxide to suIfur(VI) oxide
Trypuć M., Mazurek K., Kiełkowska U., Drużyński S.
Polish Journal of Chemical Technology
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2007
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Vol. 9, nr 3
26-28
EN
The research was conducted to determine the influence of the urea concentration in the leaching solutions on the efficiency of recovery of vanadium and iron compounds from the used vanadium catalyst from the node of oxidation of sulfur dioxide to sulfur trioxide.
10
Content available Utilization of the post-filtration lye from the SCS method of soda production
Trypuć M., Drużyński S., Kiełkowska U., Mazurek K.
Polish Journal of Chemical Technology
|
2007
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Vol. 9, nr 4
59-62
EN
The mutual solubility of salts in the NaVO3-NaNO3-H2O system was investigated at 293 - 323 K temperature range by the method of isothermal saturation of solutions. A fragment of the solubility polytherm for that system was plotted, based on the obtained data. The investigated system is a part of the quaternary NH4NO3-NaVO3-NH4VO3-NaNO3 system, and it is necessary for plotting the solubility isotherm as a planar projection according to Janecke, since it defines one edge of its square. Knowledge of the isotherm for that quaternary system is necessary to determine the optimal utilization conditions for the post-filtration lye, formed during the soda production from NaNO3 by the Solvay method, using NaVO3.
11
Content available The Influence of urea on the KHCO3 and NH4VO3 solubility in the KHCO3 + NH4VO3 + H2O system
Kiełkowska U., Trypuć M., Mazurek K., Drużyński S.
Polish Journal of Chemical Technology
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2007
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Vol. 9, nr 2
23-26
EN
The influence of urea on the vanadium(V) and potassium ion concentrations in the KHCO3 + NH4VO3 + H2O system was determined in the temperature range of 293 K to 303 K. Additionally, the solution density dependence versus the urea concentration was presented. These data are essential for the assessment of optimum operating conditions for the new production process of potassium carbonate.
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