The behaviour during thermal degradation of biomass, lignite and blends of these two fuels has been investigated. Polish lignite (Turow), pine sawdust and their blends in ratios 75% demineralised lignite + 25% ion exchanged pine and 75% ion exchanged lignite + 25% demineralised pine were used in the research. Samples were demineralised by 2M HCl to remove acid-soluble mineral matter and then ion exchanged by calcium acetate solution. The fuels were studied using a range of laboratory scale methods including TGA and DTG analysis. The influence of calcium on the devolatilization processes is discussed.
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