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Impact of Carbon Nanotubes on the Mechanical and Electrical Properties of Silicone

Sałaciński Michał, Dydek Kamil, Leski Andrzej, Kozera Rafał, Mucha Mateusz, Karczmarz Wojciech

Fatigue of Aircraft Structures

2022

Iss. 14

135--153

This paper presents the results of a structure study of a dispersion composite on a silicone matrix with a filler in the form of multi-walled carbon nanotubes (MWCNTs). The study aims to determine the effect of the filler on the composite mechanical properties and electrical conductivity. Materials that are electrically conductive and exhibit high mechanical properties can find applications in high-strain sensors. During the study, the characteristic properties of the susceptible materials, silicone alone and silicone with different filler contents (4%, 6%, and 8% by weight), were determined after curing. Microscopic observations were performed to assess the influence of carbon fillers on the material structure and to determine the level of homogeneity of the material. Examination of mechanical properties facilitated the determination of the Shor A hardness (ShA), stiffness, and Poisson’s ratio of the cured composites, depending on the nanotubes’ content. In parallel with the study of mechanical properties, the effect of loading, and the associated deformation of the samples, on the conductivity of the composite was investigated. Based on the results obtained, a discussion was carried out on the type of conductivity characteristic of silicone with different filler content as well as depending on the level of deformation of the samples.

Comparison study of the influence of carbon and halloysite nanotubes on the preparation and rheological behavior of linear low density polyethylene

Burzynski Maksymilian, Paszkiewicz Sandra, Piesowicz Elżbieta, Irska Izabela, Dydek Kamil, Boczkowska Anna, Wysocki Stanisław, Sieminski Jakub

Polimery

2020

T. 65, nr 2

95--98

Two 1D-types’ nanofillers, in the form of multi-walled carbon nanotubes (MWCNTs) and halloysite nanotubes (HNTs), were introduced in an amount of 10, 15 and 20 wt % to linear low density polyethylene (LLDPE) in order to compare their effect on rheological properties. The neat LLDPE and its nanocomposites were obtained by direct melt blending. Since rheological properties have a key impact on the processing of polymer materials, it has been determined whether and how carbon and non-carbon nanotubes affect the viscosity of the composition. It was found that the addition of MWCNTs more significantly affects both the melt viscosity as well as the storage and loss moduli of the LLDPE matrix, compared to HNTs-based nanocomposites.

Dwa rodzaje nanonapełniaczy 1D, w postaci wielościennych nanorurek węglowych (MWCNTs) oraz nanorurek haloizytowych (HNTs) wprowadzono do liniowego polietylenu małej gęstości (LLDPE) w ilości 10, 15 lub 20% mas. Nienapełniony LLDPE oraz nanokompozyty na jego osnowie otrzymano metodą bezpośredniego mieszania w stanie stopionym. Zbadano wpływ dodatku nanonapełniaczy na właściwości reologiczne wytworzonych kompozytów determinujące ich przetwórstwo. Stwierdzono, że dodatek MWCNTs do polietylenowej osnowy znacznie wyraźniej niż dodatek HNTs wpływa zarówno na zwiększenie lepkości stopu, jak ina moduły: zachowawczy oraz stratności.