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Mediation of Magnetic Interactions in Prussian Blue Family

Wasiutyński T., Bałanda M., Szeglowski Z., Zieliński P. M.

Polish Journal of Chemistry

2002

Vol. 76 / nr 2-3

377-384

Results of the AC susceptibility and DC magnetization of the family ACo[Fe(CN)6] for different cations A: Li, Na, K, Rb, Cs,NH4, N(Et)4 are presented. Differences in magnetic properties are found that can be attributed to an indirect interaction mediated by the cations. Two other compounds: A2NiII[FeII(CN)6] (A = K, Na) were also studied. The strong influence on magnetic properties due to alkaline cations was again observed.