The fate of cadmium and copper during thermal and ultrasound treatments of activated sludge was studied in terms of mixed liquor physicochemical modifications. Biochemical composition of sludge testfied to the solubilization of its biopolymers. Granulometric measurements demonstrated that ultrasound and temperature induced respectively floc disintegration and macrofloc deflocculation. The uptake of the two metals by sludge flocs was improved with an increase in temperature. Both metals were in a different way adsorbed by sludge flocs, since mass transfer improvement together with the extended surface area offered by sonicated flocs increased the cadmium adsorption. At the same time, an increase in soluble organic ligands limited copper uptake.
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