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Content available remote Analysis of the thixoability of ASTM A536 ductile iron
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Purpose: Thixoability of the ASTM A536 nodular cast iron is analyzed, it meaning its ability to hold a thixotropic semi-solid state and to be formed as such. Thixoability can be characterized by the solidification range, fraction of primary phase and sensitiveness of liquid fraction with temperature (df1/dT) within the solidification range. It is also investigated the effect of thixocasting in the microstructure of the considered alloy. Design/methodology/approach: Differential thermal analysis, differential scanning calorimetry and thermodynamic calculation package THERMOCALC were used to predict transformations temperatures involving liquid formation and df1/dT within the solidification range. Microstructures of thixotropic slurries produced by partial melting were observed. Findings: Thixoforming of ASTM A536 nodular iron can be considered in a narrow window of about 28° C, were some dissolution of graphite nodules can still be afforded; this window meaning the range of temperatures of co-existence of austenite + graphite + liquid were the eutectic transformation is taking place. At higher temperatures the dissolution of graphite nodules in liquid can be significant. Research limitations/implications: Thixoability prediction models rely on sensitive experiments as thermoanalysis, with results strongly dependent on experimental conditions; and on thermodynamic data, sometimes not available or reliable for a specific alloy composition. Practical implications: The prediction of the thixoability of a certain alloy can make it more effective its thixoprocessing, allows better control of processing parameters and quality of final product; can also subsidize modifications in the alloy to make it more suitable to semi-solid processing. Originality/value: The study of the thixoability of a nodular hypereutectic cast iron is an original subject, not available in the specialized literature, however absolutely necessary if thixoprocessing of this family of alloys is to be considered.
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