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Carbide Cutting Tool Coatings Characterization of 8YSZ

Kareem Shaimaa J., Wurood Asaad M., Abbas Sundus, Al-Ethari Haydar

Advances in Science and Technology. Research Journal

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2024

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Vol. 18, no 4

410--419

EN

Using a duplex deposition of TiO2/8YSZ on a carbide cutting tool, a successful sol-gel procedure was achieved, resulting in high homogeneity, good dispersion, and a low average value of surface roughness (223.6)nm. Thermal experiments were done to see how well the coating layers could withstand heat transfer and thermal deterioration. Residual stresses for coated and uncoated carbide cutting tools are measured after thermal shock (thermal shock). Both were immediately chilled in ice water after being heated for 90 minutes for coated inserts and 30 minutes for uncoated inserts at 500, 600, 700, 800, 900, and 1200 °C. For inserts, thermal shock from 900 °C results in significantly different damage mechanisms. The uncoated outside surface is still delineated by a crack network and is surrounded by nearby homogenous cells, but the coated insert (sol gel TBC) in this case really has a few tiny cracks beginning at the edge. The coated insert (sol-gel TBC) fails after being heated to 1200 °C and then cooled in water to freezing which is caused the start of the duplex coating degradation.

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Influence of air plasma spraying process parameters on the thermal barrier coating deposited with micro- and nanopowders

Kubaszek Tadeusz, Góral Marek, Pędrak Paweł

Materials Science Poland

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2022

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Vol. 40, No. 3

80--92

EN

This study investigates the optimal conditions to deposit a thermal barrier coating using micro- and nanopowders in the air plasma spraying (APS) process. The influence of the APS process parameters on the thickness, porosity and hardness of the yttria-stabilized zirconia (YSZ; ZrO2 × 8Y2O3) coatings deposited with a single-electrode plasma gun was determined. The temperature and velocity of melted particles were determined by the DPV diagnostic system to decrease the number of experimental processes. The current and H2 flow rate were changed in this research. Metco-6700 YSZ micropowder has already been used in plasma spray physical vapor deposition. The results of this study suggest the possibility of using it for APS. The particles of this powder are characterized by high temperature (2,700°C–2,900°C) and high speed (>380 m/s). The highest thickness of the coating was obtained with 6 NLPM (normal liter per minute) H2flow and 800 A current. Difficulties were observed with the feeding of the powder particles at higher H2flow. The results showed that using APS, deposition of Metco-6609, a nanopowder normally used in suspension plasma spraying, is possible. In this research, this powder was fed using a carrier gas. The coatings were around 40 μm thick and had high porosity. The lowest porosity of the coating was obtained at a current of 600 A and H2 flow rate of 12 NLPM. In the coatings, unmelted spherical particles were also visible.

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Synthesis of nanocrystalline Ni/Ce-YSZ powder via a polymerization route

Abolghasemi Z., Tamizifar M., Arzani K., Nemati A., Khanfekr A., Bolandi M.

Materials Science Poland

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2013

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Vol. 31, No. 3

343--349

EN

Pechini process was used for preparation of three kinds of nanocrystalline powders of yttria-stabilized zirconia (YSZ): doped with 1.5 mol% nickel oxide, doped with 15 mol% ceria, and doped with 1.5 mol% nickel oxide plus 15 mol% ceria. Zirconium chloride, yttrium nitrate, cerium nitrate, nickel nitrate, citric acid and ethylene glycol were polymerized at 80 A degrees C to produce a gel. XRD, SEM and TEM analyses were used to investigate the crystalline phases and microstructures of obtained compounds. The results of XRD revealed the formation of nanocrystalline powder at 900 A degrees C. Morphology of the powder calcined at 900 A degrees C, examined with a scanning electron microscope, showed that the presence of nickel and cerium inhibited the grain growth in the system. The average crystallite size of the material doped with nickel oxide (9.33 nm) was bigger than the one doped with cerium oxide (9.29 nm), while the YSZ doping with the two oxides simultaneously promoted the grain growth with crystallite size of 11.37 nm. Yttria-stabilized zirconia powder with a mean crystallite size of 9.997 nm was prepared successfully by this method.

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Fabrication of yttria stabilized zirconia nanoparticles by the reverse microemulsionmethod for SOFC applications

Vatansever S., Öksüzömer F., Naci Koç S., Somer M., Deligöz H., Gürkaynak M. A.

Materials Science Poland

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2010

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Vol. 28, No. 1

85--91

EN

Yttria stabilized zirconia powders were synthesized by the reverse microemulsion method. Powders were calcined from 600 °C to 1000 °C and sintered at 1450 °C. Crystalline properties and microstructure of samples were characterized by X-ray diffraction and scanning electron microscopy, respectively. Oxygen ionic conductivity was measured by electrochemical impedance spectroscopy. Sizes of yttria stabilized zirconia particles calcined at 1000 °C are lower than 100 nm, and approximately, 1 žm grain was obtained after sintering at 1450 °C.