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Flotation separation of wolframite from quartz using N-oleoyl sarcosine acid as collector

Xian-Ping L., Feng B., Xianwen Z., Li-Yying L., Zheng-He X.

Physicochemical Problems of Mineral Processing

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2017

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Vol. 53, iss. 1

34--41

EN

In this study the collecting power of N-oleoyl sarcosine acid towards wolframite and quartz was studied using flotation. The adsorption mechanism was also discussed based on the results from adsorption experiments, zeta potential measurements and infrared spectroscopy study. The flotation results showed that N-oleoyl sarcosine acid showed a good collecting power towards wolframite, and the optimal flotation pH = 7 was obtained. However, the collecting power of N-oleoyl sarcosine acid towards quartz was weak. Therefore, the flotation separation of wolframite from quartz can be performed using N-oleoyl sarcosine acid as a collector. The adsorption tests and electrokinetic studies showed that N-oleoyl sarcosine acid adsorbed only on the wolframite surface. Additionally, the results from the infrared spectroscopy study confirmed that N-oleoyl sarcosine acid is adsorbed on the wolframite surface, and the metal complex (ferriccarboxylate) maybe the major adsorbed species.

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Beneficial effects and mechanism of lead ion on wolframite flotation

Yang S., Qiu X., Peng T., Chang Z., Feng Q., Zhong C.

Physicochemical Problems of Mineral Processing

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2016

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Vol. 52, iss. 2

855--873

EN

In this study the effects and mechanism of lead ions influence on wolframite flotation with benzohydroxamic acid (BHA) were studied through micro-flotation, adsorption experiments, zeta potential measurements, logarithmic concentration diagram, and X-ray photoelectron spectroscopy. It was observed that lead ions could significantly enhance the recovery of wolframite in flotation and adsorption density of collector BHA onto the wolframite surface. The results showed that Pb existed in the forms of lead ion, monohydric lead, and lead hydroxide at the water-wolframite interface respectively, at three pH ranges. They increased the zeta potential of wolframite. However, the zeta potential of wolframite was still negative, resulting in repulsive electrostatic force to anionic collector BHA. Combining with XPS spectra, it revealed the chemisorption of BHA onto the wolframite surface. In addition, PbO or Pb(OH)2 was observed on the wolframite surface due to the reaction between lead ions and wolframite. These reaction products increased the adsorption site of BHA on the wolframite surface because Pb-hydroxamate was found on the wolframite surface.

3

Relationship between flotation and Fe/Mn ratio of wolframite with benzohydroxamic acid and sodium oleate as collectors

Yang S., Feng Q., Qiu X., Gao Y., Xie Z.

Physicochemical Problems of Mineral Processing

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2014

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Vol. 50, iss. 2

747--758

EN

Several studies revealed that flotation of wolframite changes with different Fe/Mn ratios, but they did not reach a consensus. This relationship in the presence of benzohydroxamic acid (BHA) and sodium oleate (NaOl) as collectors was studied in this paper through comparison of probability distribution curve of wolframite with different Fe/Mn ratios between the raw ore and the flotation concentrate, the pure mineral flotation and solution chemistry of flotation. The results showed that wolframite with high Fe/Mn ratio showed higher flotation with BHA as a collector while the flotation behavior of wolframite was completely opposite with NaOl as a collector. Besides, the calculations of chemical equilibrium in the solution were plotted as ΔG°-pH graphs. The results revealed that the flotation of wolframite may be determined by the interaction between BHA and ferric(II) ion or between NaOl and manganous ion. From the perspective of collector mixture, the results also explain the high collecting capability of the BHA/NaOl collector mixture, which can be defined as “functional complementation”.

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Polymetallic mineralization in Ediacaran sediments in the Żarki-Kotowice area, Poland

Karwowski Ł., Markowiak M.

Mineralogia

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2012

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Vol. 43, iss. 3/4

199--212

EN

In one small mineral vein in core from borehole 144-Ż in the Żarki-Kotowice area, almost all of the ore minerals known from related deposits in the vicinity occur. Some of the minerals in the vein described in this paper, namely, nickeline, hessite, native silver and minerals of the cobaltite-gersdorffite group, have not previously been reported from elsewhere in the Kraków-Lubliniec tectonic zone. The identified minerals are chalcopyrite, pyrite, marcasite, sphalerite, Co-rich pyrite, tennantite, tetrahedrite, bornite, galena, magnetite, hematite, cassiterite, pyrrhotite, wolframite (ferberite), scheelite, molybdenite, nickeline, minerals of the cobaltitegersdorffite group, carrollite, hessite and native silver. Moreover, native bismuth, bismuthinite, a Cu- and Ag-rich sulfosalt of Bi (cuprobismutite) and Ni-rich pyrite also occur in the vein. We suggest that, the ore mineralization from the borehole probably reflects post-magmatic hydrothermal activity related to an unseen granitic intrusion located under the Mesozoic sediments in the Żarki-Pilica area.