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EN
The article presents the preliminary results of pore-water chemistry studies of the entire Upper Pleistocene loess-paleosol sequence in Zaprężyn (SW Poland). The pore-water chemical composition provides information about behaviour of the elements in the loess profile during the rock-water interactions. The applied method of ex situ water extraction allows only obtaining slightly bound water, which determines physicochemical parameters of the ground. The considerable variability of the values of pH, EC and concentrations of Al3+, Fe3+, Mn2+, Mg2+, Ca2+, Na+, K+, SO42-, Cl- ions and SiO2 was caused by stratification of sediments. The effect of reduced-permeability barrier on the increased concentrations of some ions was also found.
EN
Diagenetic illite tends to crystallize most often as fibres and it forms net-like textures reducing filtration abilities of sandstones. Rocks containing this type of illite show a very low permeability or may even be impermeable. K-Ar datings of crystallization of these fibres define the time when permeability was reduced and duration of the post-depositional period when the deposits were permeable for pore fluids, including gaseous and liquid hydrocarbons. Clay fractions <0.2 ěm and <0.3 ěm were isolated from 12 samples of the Rotliegend sandstones fromWestern Poland in order to define the K-Ar age of illite. The results of investigations show that this age from the fraction <0.2 ěm falls between 187.1 and 113.6Ma (tab. 1), that covers a long period since early Jurassic to late Cretaceous. The determination of 18O in illite (15.1–15.9‰SMOW), performed in East Kilbride laboratory, and calculations of hypothetic temperatures of illite crystallization (125–173°C) show that it crystallized from pore waters of marine origin and with 18O values ranging from 4.3 to 7.5‰ SMOW, which probably infiltrated from evaporitic Zechstein deposits.
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