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Investigation into the effect of waste engine oil and vegetable oil recycling agents on the performance of laboratory-aged bitumen

Ali Basit, Li Peilong, Khan Diyar, Hasan Mohd Rosli Mohd, Khan Waseem Akhtar

Budownictwo i Architektura

2024

Vol. 23, no 1

33--54

The pavement recycling method is one of the practical ways to integrate sustainable development into transportation infrastructure, and it has been adopted worldwide. The use of reclaimed asphalt pavement (RAP) in new asphalt highways is limited due to the ageing effects caused by UV damage and weathering on the asphalt binder. To address this issue, waste vegetable oil (WVO) and waste engine oil (WEO) have been proposed as potential rejuvenating agents to enhance the recyclability of pavements containing RAP. This study evaluated the effectiveness of WEO and WVO as chemical rejuvenating agents through various tests on both aged and virgin asphalt binders. The tests included measurements of ductility, fire, and flash points, softening points, and penetration. The results indicate that the addition of WEO and WVO can improve the low-temperature properties of asphalt binders when mixed with RAP, resulting in reduced stiffness. The mixture containing WEO and WVO exhibited improved stability compared to the control, suggesting enhanced flow with increasing waste oil content in comparison to aged binder, albeit with slightly reduced flow compared to the virgin binder. This study demonstrates the potential of WEO and WVO as recycling agents to enhance the performance of bituminous mixes incorporating RAP.

Metoda recyklingu nawierzchni drogowych jest jednym z praktycznych sposobów wdrażania zrównoważonego rozwoju w infrastrukturę transportową i została przyjęta na całym świecie. Użycie odzyskanego asfaltu drogowego (RAP) w nowych autostradach asfaltowych jest ograniczone z powodu efektów starzenia spowodowanych uszkodzeniami UV i wpływem warunków atmosferycznych na spoiwo asfaltowe. Aby rozwiązać ten problem, zaproponowano wykorzystanie odpadowego oleju roślinnego (WVO) oraz odpadowego oleju silnikowego (WEO) jako potencjalnych środków odmładzających, mających na celu zwiększenie możliwości recyklingu nawierzchni zawierających RAP. Niniejsze badanie oceniło skuteczność WEO i WVO jako chemicznych środków odmładzających poprzez różne testy na starzonych i świeżych spoiwach asfaltowych. Testy obejmowały pomiary plastyczności, punktów zapłonu, miękkości oraz penetracji. Wyniki wskazują, że dodatek WEO i WVO może poprawić właściwości asfaltu przy niskich temperaturach, gdy jest mieszany z RAP, co skutkuje zmniejszeniem sztywności. Mieszanka zawierająca WEO i WVO wykazała lepszą stabilność w porównaniu do kontrolnej mieszanki, wskazując na lepszy przepływ przy wzroście zawartości odpadowego oleju w porównaniu do starzonego spoiwa, choć z nieco gorszym przepływem w porównaniu do spoiwa świeżego. Badanie to demonstruje potencjał WEO i WVO jako środków recyklingowych do poprawy wydajności mieszanki bitumicznej zawierającej RAP.

Enhanced separation efficiency of low–rank coal using waste engine oil as a flotation collector

Li Ming, Xia Yangchao, Guo Fangyu, Rong Guoqiang, Li Guosheng, Xu Baolin, Xing Yaowen, Gui Xiahui

Physicochemical Problems of Mineral Processing

2020

Vol. 56, iss. 2

252--263

Because of the rich oxygen-containing functional groups and developed pores on the Surface of low-rank coal, it is difficult to realize efficient separation during low-rank coal flotation using common oil collectors. Waste engine oil (WEO) is abundant in polar oxygen-containing functional groups and could be an alternative collector. In this study, the effect of WEO on low-rank coal floatation was assessed and engine oil (EO) was also used for comparison. The results show that the separation efficiency of low-rank coal can be significantly improved using WEO; additionally, 96.73% of the clean coal yield can be obtained when the WEO dosage was only 4 kg/t. Compared with EO, the bubble–particle induction time in the presence of WEO shortened from 430 to 220 ms. Moreover, more low-rank coal particles were captured and adhered to the bubble surface using WEO, which indicated a higher probability of bubble–particle attachment. Nonpolar components, polar components and metal ions synergistically promote the flotation separation enhancement of low-rank coal using WEO.

Electricity production from waste engine oil from agricultural machinery

Włodarczyk P. P., Włodarczyk B.

Infrastruktura i Ekologia Terenów Wiejskich

2017

nr IV/2

1609--1618

As fuel for fuel cells can be used various substances, but generally fuel cells are powered by hydrogen. However, problems with the storage of hydrogen are the reason for the search of new fuels for fuel cells. Moreover, annually are produced huge amount of waste oils. These oils must be directed to purification and processing. It would be important to use waste engine oil as fuel for fuel cell to direct electricity production without intermediate stage e.g. combustion. The paper presents the possibility of using waste engine oil as fuel for fuel cell. The oil does not have the feature of electrical conductivity, for this reason a detergent was used for dissolving oil in an electrolyte. So, the work shows possible electrooxidation of waste engine oil (Turdus 15W40 from agriculture machinery) emulsion on a platinum electrode in an aqueous solution of H2SO4. Researches were done by the method of polarizing curves of electrooxidation of waste engine oil emulsion in glass vessel, on a smooth platinum electrode with potentiostat. In any case, the process of electrooxidation of waste engine oil emulsion occurred. A current density of about 6-20 mA/cm2 was obtained for all concentrations of waste engine oil. The highest results of the potential were obtained at temperature of 333K (25 mA/cm2 ). A fundamental possibility of electrooxidation of waste engine oil (Turdus 15W40) emulsion on platinum smooth electrode in acid electrolyte (aqueous solution of H2SO4) was presented in this paper. The obtained current density and power of glass fuel cell is low, but it was demonstrated a fundamental possibility of electricity production in fuel cell powering with waste engine oil.