Celem przeprowadzonych badań było otrzymanie cienkich warstw SnO2 na powierzchniach szklanych przy użyciu techniki zol-żel, z zastosowaniem organicznych związków cyny. Warstwy otrzymywano przez nanoszenie zolu SnO2 w metanolu techniką dip coating. Otrzymana warstwa była następnie poddawana kalcynacji w atmosferze utleniającej. Otrzymano serię materiałów zawierających od 1. do 12. warstw SnO2 na powierzchni podłoża szklanego. Uzyskane warstwy poddano charakterystyce za pomocą techniki XRD, SEM, SEM-EDS, UV/VIS. Równolegle przeprowadzono badania czasowo-rozdzielcze procesu schnięcia warstwy z wykorzystaniem techniki FT-IR (ATR).
EN
The aim of the study was to obtain SnO2 thin films on glass using a sol-gel technique and organic tin compounds. The layers were prepared by dip coating deposition of SnO2 sol in methanol. The resulting layer was then subjected to a process of calcining in an oxidizing atmosphere. To give a series of materials comprising from one to twelve layers of SnO2 on the surface of the glass substrate. The obtained film was subjected to characterization by XRD, SEM, SEM-EDS and UV-Vis technique. Above that time-resolved tests of the layer drying process using the technique of FT-IR (ATR) were carried out.
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During last years protection of the environment is one of the important problems that should be solved by modern technology. The important problems are toxic gases emitted by conventional power plants. One of the methods that contribute to decreasing air pollution is manufacturing of cheap solar energy devices that could be applied in households. Among different type of fabrication technology of solar cells, DSSC technology looks like one of the interesting because it is relatively simple and low cost technology. Nowadays a lot of researcher groups making investigations to improve its setup, to get the cost reduction. The methods to achieve this goal were proposed in ISE (Germany) as a concept of monolithic dye sensitised solar cell. One of the ideas of this solar cells setup is replacing expensive TCO electrode by much cheaper graphite electrode. Replacing TCO glass by graphite layer has to be done only in case of comparable properties of those both electrodes. There are some tested ideas of manufacturing that electrode and some of them are successfully applied. Presented work has been focused on preparation graphite conductive electrode for DSSC technology application, fabricated by screen–printing technique. Investigations concern new graphite past composition suitable for graphite layer preparation. It was been found that applying additive of titanium organic compound (Tyzor GBA) to the past composition result in good properties, characterised by low resistance and good adhesion between graphite particles in the printed layer. Some tested layers prepared from proposed paste compositions characterised by better conductivity then applied in conventional DSSC cells counter electrode. The optimal addition of the modifier has not fixed yet. Among tested pastes the most promising results has been achieved for paste contained the biggest amount of Tyzor GBA.
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W artykule zamieszczono wyniki badań przewodnictwa warstw grafitowych nanoszonych metodą sitodruku przeznaczonych do zastosowania w ogniwach fotowoltaicznych. Warstwy te wytwarzane są za pomocą past zawierających substancje organiczne, które mogę być z niej usunięte w temperaturze do 350°C co zapewnia dobre przewodnictwo elektryczne. Warstwa taka jest zwarta zapewniając odpowiednie połączenia elektryczne pomiędzy cząstkami grafitu.
EN
The article presents the results of the studies on conductive behaviour of graphite layers applied by the technique of screen process and assigned for operation in photovoltaic cells. The layers are produced using pastes containing some organic matters, which can be removed at a temperature of up to 350°C , thus ensuring a good electric conduction. A layer made by this technique is very compact which makes the graphite particles come closely into contact with each other.
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