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The analysis of strength properties of ceramic preforms for infiltration process

Putyra P., Kurtyka P., Jaworska L., Podsiadło M., Smuk B.

Archives of Materials Science and Engineering

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2008

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Vol. 33, nr 2

97-100

EN

Purpose: The goal of this work is the optimization of sintering process of the ceramic preforms based on Si3N4 and Al2O3-Ti(C,N) materials. The influence of pore forming additives on porosity, microstructures and compressive strength are investigated. The aim of this study is to obtain the nitrides and carbides base preforms material for the infiltration process of molten aluminium alloys. Design/methodology/approach: The method of obtaining the silicon nitride and oxide-carbonitride porous preform for the infitration process is the free sintering process. The preforms were produced by the mixing of ceramic powders with organic binders, drying and sintering. Porosity, density were measured for the materials. Microstructure observation was carried out using scanning microscope. The compressive strength of Si3N4 and Al2O3-Ti(C,N) porous preforms were investigated. Findings: For sintered porous Si3N4 preforms, influence of the porous forming additives on material porosity is observed. Compressive strengths of Si3N4 were in the range of 2.9-4.8 MPa. The highest value of the compressive strength was obtained for Al2O3-Ti(C,N) preform with 8 wt.% of tylose and 25 wt.% of glykol. For these materials compressive strength were in the range of 13.2 up to 14.3 MPa. In spite of lower value of the compressive strength for Si3N4 preforms, this material exhibits high shock thermal resistance. Practical implications: Pressureless infiltration of molten metals into ceramics is the most cost-effective approach to liquid-metal processing of MMCs. Metal matrix composites are applied widely in aircraft production technologies and defence technology. Originality/value: Infiltration of molten metals into porous ceramic preforms is the only technique suitable for the fabrication of high volume fraction of ceramic materials in MMCs. Infiltration process generates thermal stresses in the ceramics preforms. The thermal shock resistance of Al2O3 is lower than Si3N4 or Al2O3-Ti(C,N) materials. New kinds of porous materials were obtained.

2

Nadmiarowe fazy w wysokoazotowych stalach austenitycznych

Kaputkina L., Svjażin A., Siwka J., Prokoszkina W.

Hutnik, Wiadomości Hutnicze

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2007

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Vol. 74, nr 7

357-363

PL

Badano zmiany zawartości azotu w austenicie po nagrzewaniu próbek do różnych temperatur i ich wygrzewaniu w różnych czasach. Ustalono, że w warunkach typowego nagrzewania w celu przesycenia bazowej stali Crl8Nil0Ti w jej strukturze występują nie rozpuszczone w roztworze starym azotki, których ilość zwiększa się ze wzrostem zawartości azotu w stali. Jest możliwe prawie całkowite rozpuszczenie się azotków przez nagrzanie metalu do temperatury 1200 °C i wygrzewanie go przez czas dłuższy niż 30 min. Zawartość azotu w austenitycznych stalach wysokoazotowych powinna być zbilansowana z zawartością innych pierwiastków stopowych w zależności od pożądanej struktury: austenit lub austenit i fazy nadmiarowe.

EN

Variations in the nitrogen content of austenite after heating the specimens up to different temperatures and then soaking them for different periods of time were investigated. It has been found that, under the conditions of typical heating to supersaturate the base Cr18Ni10Ti steel, nitrides undissolved in the solid solution occur in its structure, the amount of which increases with increasing nitrogen content of steel. Almost complete dissolution of nitrides is possible by heating the metal up to a temperature of 1200 °C and then soaking it for a period of time not longer than 30 min. The nitrogen content of high-nitrogen austenitic steels should be balanced with the contents of other alloy-forming elements, depending on the desired structure: austenite or austenite and excess phases.

3

Nitride and carbide preforms for infiltration process

Sobczak N., Jaworska L., Podsiadło M., Smuk B., Nowak R., Kurtyka P., Twardowska A.

Archives of Materials Science and Engineering

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2007

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Vol. 28, nr 11

653-656

EN

Purpose: Infiltration of molten metals into porous ceramic preforms is the only technique suitable for the fabrication of high volume fraction of ceramic materials in MMCs. The most popular material for porous preforms is Al2O3 because of its low cost. Infiltration process generates thermal stresses in the Al2O3 preforms. The thermal shock resistance of Al2O3 is lower than for Si3N4 or Al2O3/TiC+TiN materials. The aim of this study is to obtain the nitride and carbide base preforms material for the infiltration process of molten aluminium alloys. Design/methodology/approach: The method of obtaining the silicon nitride and oxide-carbonitride porous preform for the infiltration process is the free sintering process. Some of selected properties of this material are presented. The preforms were produced by the mixing of ceramic powders with organic binders, followed by forming, drying and firing. Ceramic preforms of 65% porosity were produced. Microscopic investigations revealed good joints between the ceramic particles. Findings: The material consist of the base component (90 wt.% of α-Si3N4, 5 wt.% of Al2O3, 5 wt.% of Y2O3), which were mixed with 40 wt.% of polyethylene glycol 6000 (mixed in Turbula) porosity is 25.7 %. The higher value of porosity 66.6% was obtained for material with 20 wt.% tylose. The grain size of Si3N4 and method of the mixtures preparing (mixing with or without milling) have the significant influence on compacts' porosity. For 68 wt.% Al2O3, 2 wt.% ZrO2 and 30 wt.% Ti(C,N) with addition of glycol 6000, the value of porosity is 67%.-Si3N4 material produced shows strong bonding with aluminium and AlSi11 aluminium alloy. Practical implications: Pressureless infiltration of molten metals into ceramics is the most cost-effective approach to liquid-metal processing of MMCs. Metal matrix composites are applied widely in aircraft production technologies and defence technology. Originality/value: Compared to widely used alumina performs, those made from non-oxide ceramics demonstrate better physicochemical compatibility with aluminium alloys. New kinds of porous materials were obtained.

4

Thermodynamic analysis of the kinetics of carbonitride precipitation in HSLA steels.

Adrian H.

Inżynieria Materiałowa

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1998

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R. XIX, nr 3

171-178

EN

Precipitation of carbonitride in HSLA steel containing up to three microalloying elements was analysed, using classical theory of diffusion controlled nucleation. For this purpose the driving force for carbonitride nucleation is calculated using a thermodynamic model. The results of calculation show, that the critical nucleus formed at high temperature is richer in N and element having the highest chemical affinity for N compare to the bulk precipitate at equilibrium. On the basis of analysis a kinetic model was developed for predicting start times, for precipitation of carbonitride in austenite.

5

New processing method for the preparation of interstitially modified Sm-Fe intermetallics.

Jakubowicz J., Jurczyk M.

Inżynieria Materiałowa

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1998

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R. XIX, nr 4

827-831

EN

Sm2Fe17-nitrides and Sm2Fe-17-carbonitrides, which have the rhombohedral Th2Zn17 type structure have been synthesized and studied by XRD, SEM and magnetometry. A coercivity of 2.1 MA m -1 has been obtained for Sm2Fe17N-3 powder prepared by HEBM, and a simple one-step mechanical grinding of Sm2Fe17, with organic ring compounds has been used to produce an anisotropic powder. This study demonstrates that formation of an anisotropic Sm2Fe17(C,N)x powders by mechanochemical reaction between Sm2Fe17 and organic ring compounds has a significant potential for the synthesis of powders in an economic method. These materials show intrinsic coercivities, JHc up to 0.55 MA m-1 at room temperature.

6

Analysis of the properties of carbonitrides in HSLA steels.

Osuch W., Adrian H.

Inżynieria Materiałowa

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1998

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R. XIX, nr 3

303-306

EN

The results of complex analysis of the size of (Ti, Nb, V) (C, N) carbonitride particles are presented. The morphology of particles, their size distributions and chemical composition were investigated. The results of investigations were compared with calculated data obtained using the thermodynamic model for carbonitrides precipitation in HSLA steels.