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Complexes of Benzeneboronic Acid and Triphenylboroxin with Amines

Sporzyński A., Lewandowski M., Zarychta B., Zaleski J.

Polish Journal of Chemistry

2005

Vol. 79 / nr 7

1099-1105

Benzeneboronic acid reacts with aliphatic amines to give a stable 1:1 complex formed by triphenylboroxin with an amine molecule. The structure of the complex of triphenylboroxin with n-butylamine (1) has been determined by X-rays. Several complexes with other amines have been characterized spectroscopically. The equilibrium in the system depends on the amine and the solvent nature.