Wyniki wyszukiwania - BazTech

Ograniczanie wyników

Znaleziono wyników: 2

Liczba wyników na stronie

Wyniki wyszukiwania

Wyszukiwano:
w słowach kluczowych: titania layer

Sortuj według:

Ogranicz wyniki do:

Cost-effective titania layers over 100 nm thick : effect of annealing on the structural, morphological, and optical properties

Zięba Magdalena, Tyszkiewicz Cuma, Gondek Ewa, Wojtasik Katarzyna, Nizioł Jacek, Dorosz Dominik, Starzyk Bartłomiej, Szymczak Patryk, Pakieła Wojciech, Rogoziński Roman, Karasiński Paweł

Opto-Electronics Review

2023

Vol. 31, No. 4

art. no. e147913

Titania dioxide (TiO₂) layers were synthesized via the acid-catalysed sol-gel route using titania (IV) ethoxide, and then annealed at temperatures varying in the range of 150-700 °C. The research concerned the effect of annealing temperature on the structure of TiO₂ layers, their surface morphology, and their optical properties. Further, X-ray diffractometry, and Raman spectroscopy were used to determine the structure of TiO₂ layers. Scanning electron and atomic force microscopy were used to study the surface morphology of TiO₂ layers. Transmittance, reflectance, absorption edge, and optical homogeneity were investigated by UV-VIS spectrophotometry, while the refractive index and thicknesses of TiO₂ layers were measured using a monochromatic ellipsometer. Chromatic dispersion characteristics of the complex refractive index were determined using spectroscopic ellipsometry. Structural studies have shown that the TiO₂ layers annealed at temperatures up to 300 °C are amorphous, while those annealed at temperatures exceeding 300 °C are polycrystalline containing only anatase nanocrystals with sizes increasing from 6 to 20 nm with the increase of the annealing temperature. Investigations on the surface morphology of TiO₂ layers have shown that the surface roughness increases with the increase in annealing temperature. Spectrophotometric investigations have shown that TiO₂ layers are homogeneous and the width of the indirect optical band gap varies with annealing temperature from 3.53 eV to 3.73 eV.

Preparation and characterization of hydrothermally treated hydroxyapatite containing titania layer on commercially pure titanium

Teker D., Muhaffel F., Cimenoglu H.

Archives of Materials Science and Engineering

2014

Vol. 68, nr 1

5--9

Purpose: To investigate the effect of hydrothermal treatment (HT) on bioactivity of micro arc oxidized (MAO) and MAO/) commercially pure titanium (Cp-Ti). Design/methodology/approach: Cp-Ti (Grade IV) samples were oxidized in order to generate titania layer via micro arc oxidation (MAO) process. The samples were treated at 400 V for 5 minutes in a calcium acetate hydrate and disodium hydrogen phosphate anhydrous containing electrolyte. Subsequently, hydrothermal treatment (HT) was applied on oxidized surface in an autoclave with a water solution whose pH adjusted to 11.0-11.5 by adding NaOH, at 200 and 230°C for 2.5, 5 and 10 h and cooled in the autoclave to achieve improved bioactivity behaviour. The bioactivity tests were employed by soaking the samples in a 1.5X simulated body fluid (SBF) to characterize biological response of treated surfaces. The mean elemental composition, surface and cross-sectional morphology, phase composition and surface roughness were examined by energy dispersive spectrometer (EDS) equipped scanning electron microscopy (SEM), X-ray diffractometer (XRD) and profilometer, respectively. Findings: It is found that after MAO+HT process, the surface roughness of the samples was reduced due to the homogeneous distribution of HA agglomerates. The improved surface properties of CP-Ti modified with micro arc oxidation and hydrothermal treatment showed that it can be a good potential candidate for biomedical applications instead of bare CP-Ti. Originality/value: Different HT conditions parameters and the hydroxyapatite crystallization mechanism on oxidized surfaces of the Cp-Ti samples was examined.