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1 2004

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Synthesis, Structure and Non-Linear Optical Properties of a Copper(II) Ethyl Bisulfate Two-Dimensional Supramolecular Compound {Cu(Him)4(Cu(Him)4(CH3CH2OSO3H)2]

Li Y., Lu J., Cui X., Xu J., Sun Y., Pan L., Bie H., Zhang X.

Polish Journal of Chemistry

2004

Vol. 78 / nr 6

779-787

A novel copper(II) ethyl bisulfate complex [Cu(Him)4(Eb)2] 1 (Him = imidazole, Eb = ethyl bisulfate) has been prepared and characterized by means of elemental analysis, IR and ESR. The structure was determined by single crystal X-ray diffraction analysis, which suggests that compound 1 exhibits a two-dimensional supramolecular structure through hydrogen bonds. Compound 1 displays strong third-order non-linear optical (NLO) absorption and refraction with absorption coefficient _2 1.10_10-11 m_w-1 and refractive index n2 5.60_10-16m2_w-1. The third-order non-linear optical susceptibility _(3) of compound 1 is 3.07_10-10 esu.