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1 Bulletin of the Polish Academy of Sciences. Technical Sciences

1 2021

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Multivoltaic GaSe clathrate as new hybrid functional nanostructure

Ivashchyshyn Fedir, Pidluzhna Anna, Calus Dariusz, Hryhorchak Orest, Chabecki Piotr, Makarchuk Oleksandr

Bulletin of the Polish Academy of Sciences. Technical Sciences

2021

Vol. 69, nr 2

art. no. e136726

The electrical properties and behaviour in constant magnetic field of fourfold expanded GaSe matrix intercalated with SmCl 3 guest were investigated by means of impedance spectroscopy and cyclic voltammetry. It was determined that the synthesized GaSe< SmCl 3> clathrate of 4-fold expansion demonstrates the coexistence of mechanisms of generation, transformation and accumulation of electric energy on a quantum level. These mechanisms are driven from external sources of magnetic, thermal and electric field without Faradaic reactions. Therefore, investigated GaSe< SmCl 3> structure is of great attraction in multivoltaics as a prototype of new class of materials. Quantum mechanical model of electro motive force of spin nature is proposed. The main focus of work lies in the prospects of synthesized clathrates for the development of power nanosources and gyrator-free delay nanolines controlled by means of magnetic field.