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Description of experimental data in thermodynamics analysis of binary solutions.

Jarosz P., Sukiennik M., Gargul K., Gierlotka W.

Inżynieria Materiałowa

2001

R. XXII, nr 4

392-393

In this work one analysed influence of manner of description of experimental data on counted values of thermodynamical function in binary solution. One ascertained, that large meanings in widened thermodynamical analysis of binary solutions has acquaintance of structural coefficients. It is possible to obtain the reliable results from phase diagram only using interpolation methods. One showed on the ground of thermodynamical analysis of solution Hg-In, that description of activity with functions cubic spline permits on qualification stochiometrics of intermetallic compounds.