Biopolymer carboxymethyl tamarind seed kernel polysaccharide (CMTSP) was synthesized by the reaction of tamarind kernel powder (TKP) of Tamarindus indica L. with monochloroacetic acid by an improved method. The synthesis was conducted in presence of sodium hydroxide at optimized conditions of time, temperature, concentrations of TKP, MA, sodium hydroxide. Tamarind seed polysaccharide (TSP) was also extracted from TKP by boiling distilled water. The chemical structure of TKP, TSP and CMTSP were analyzed by the ATR-FTIR. When TKP, TSP, and CMTSP's comparative physico-mechanical properties were examined and compared, CMTSP performed better due to increase in viscosity, water solubility and tensile properties.
This study evaluates the feasibility of using tamarind (Tamarindus indica) seed powder for de-fluoridation of fluoride contaminated water. Batch study confirmed that tamarind seeds in dry powder form could remove 87% of fluoride from water. This bio-sorbent can be used effectively in areas where fluoride concentrations are above the permissible limits of 1.5 mg·l-1 as per WHO Standard, 1984. Tamarind seed powder was incorporated in a matrix of sodium alginate and made into gel-beads. The beads were tested for de-fluoridation efficiency by conducting column studies. The effect of various factors, such as flow rate, retention time, and the number of runs on the efficacy of fluoride removal was also studied. The results revealed that flow rate did not seem to have much effect on the percentage fluoride removal but the fluoride concentration decreased drastically upon greater retention time and multiple runs.
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