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EN
Hydromorphological assessment of watercourses provides much valuable information about the riverbed and its immediate surroundings, including the influence of geographical environmental factors along with anthropogenic pressures in the catchment area. This paper presents diversity of hydromorphological conditions of 77 sections located on 39 watercourses in southern Poland in three European ecoregions: Eastern Plains, Central Plains and the Carpathians. The study was based on the Hydromorphological Index for Rivers (HIR) method and two sub-indices: Hydromorphological Diversity Score (HDS) and Hydromorphological Modification Score (HMS). Basic and multi-dimensional statistical analyses were performed to identify the main gradients of the geographical environment and the variables that contribute most to the total variability of HIR. The highest mean HIR values were recorded in the Carpathians ecoregion, then in the Central Plains and the lowest in the Eastern Plains, 0.70, 0.67 and 0.58, respectively. Significant differences were found between the Carpathians and Eastern Plains ecoregions in HIR values obtained. Hydromorphological differentiation is most influenced by altitude and geological type. The cluster analysis enabled two main groups of watercourses to be distinguished – the first one was dominated by variables showing HMS > HDS relationship, while the second one was dominated by HDS > HMS relationship. Multi-dimensional analysis provided additional information on the relationships between the variables and the sections studied. The greatest positive impact on the formation of the final HIR value had the variation of the riverbed slope and natural morphological elements of the bed bottom, while the greatest negative impact on HIR had the transformations observed in spot-check.
EN
The study analyzes changes in the physico-chemical parameters in a 400 cm2 artificial water reservoir with distilled water, exposed to a 2-week (±2 days) period of atmospheric conditions in Krakow. After nearly 500 days, dry and wet deposition caused a shift from neutral to acidic pH levels (7.30–5.12, averaging 6.22 pH) and an average electric conductivity of 19.5 µS/cm (1.6–143.0 µS/cm). The study investigated chemical and biological pollutants, including pollen and fungal spores. Three distinct air quality periods were identified: (1) characterized by vehicle and combustion-related pollutants (Oct-Jan), (2) a transitional phase with increased biological particles (Feb-May), and (3) dominated by pollen and fungal spores (Jun-Sep). Despite peak air pollution in the warmest months, air temperature showed an inverse relationship with pollutant concentration, possibly due to decreased air humidity. Precipitation positively impacted air quality. The artificial reservoir received a total of 0.7 kg of air pollutants (723.6mg/m3 of surface water table). This corresponds to an annual load of 0.5 kg (551.4 mg) and a daily load of 1.51 mg. The reservoir’s pollutant capture capacity was estimated at 28% ±21% (mean±SD), with a critical value of 12%. The study evaluated Krakow’s surface water reservoirs’ capacity to mitigate air pollution, indicating potential benefits for urban air quality.
PL
W artykule przedstawiono problem intensyfikującego wpływu procesu koagulacji na korozyjne właściwości wody, na przykładzie przeprowadzonych badań nad stabilnością chemiczną wody powierzchniowej po koagulacji wzrastającymi dawkami siarczanu glinu. Omówiono wyniki przeprowadzonych badań, metody zastosowane do oceny stabilności chemicznej analizowanej wody przy wykorzystaniu różnych indeksów stabilności oraz porównanie ich wskazań.
EN
The article presents the problem of the intensifying influence of the coagulation process on the corrosive properties of water, based on the example of conducted research on the chemical stability of surface water after coagulation with increasing doses of aluminum sulphate. The results of research, methods used to assess the chemical stability of the analyzed water with the use of various stability indices and the comparison of their indications are discussed.
EN
In recent decades, the province of Taza has undergone extensive agricultural modernization, marked by an increase in industrial units such as modern oil mills and olive canneries. At the same time, rapid population growth has exacerbated an important problem, the deterioration of the quality of water resources in limited quantities. This study explored the heart of matter by meticulously sampling physico-chemical and bacteriological parameters at eight strategically chosen sites. Conducted in late July 2021, the survey focused on the surface waters of the Innaouene River, providing a timely and insightful examination of the complex dynamics of water quality in the context of modernization and demographic change. This work focused on the determination of physicochemical and microbiological parameters of water. The results of the analyses show that this river is subject to multiple constraints and reaches its tolerance level on most of its sections. A multivariate statistical approach: principal component analysis (PCA) has shown that water pollution in the Innaouene River is mainly related to untreated wastewater discharges into streams. Water quality is considered bad to very bad. Therefore, ecological and health impacts can occur.
PL
W artykule przedstawiono dowody wskazujące na obecność hormonów i antybiotyków w środowisku, a także omówiono potencjalne źródła tego typu zanieczyszczeń. Z analizy obowiązujących ustaw i dyrektyw w Polsce oraz Unii Europejskiej dotyczących jakości wód powierzchniowych i tych do spożycia wynika, że obecność farmaceutyków, nie jest objęta obowiązkiem kontroli. W celu poprawy jakości wody konieczne jest zwiększenie świadomości społecznej na temat małych zasobów wodnych oraz realnego wpływu każdego człowieka na jakość wody, a także szczegółowe regulacje prawne dotyczące mikrozanieczyszczeń.
EN
This article presents a compilation of research results indicating the presence of hormones and antibiotics in the environment, and identtfies potential sourcesof these contaminants. An analysis of the current laws and directives in Poland and the European Union concerning the guality of surface and drinking water shows that, of the wide range of pharmaceuticals, the concentrations of only some of them are subject to mandatory control. In order to improve water quality, it is necessary to increase public awareness of smali water resources and the real impact of each individual on water quality, as well as specific legal regulations on micropollutants.
PL
Chloridazon był herbicydem stosowanym w uprawach buraka cukrowego, powodował hamowanie procesu fotosyntezy jednorocznych chwastów szerokolistnych. W ostatnich dziesięcioleciach chloridazon uznawano za nieszkodliwy, dlatego był chętnie stosowany przez rolników w wielu krajach. Rozkłada się on na dwa metabolity: chloridazon-desfenyl i chloridazon-metylo-desfenyl. Ze względu na swoją polarność i rozpuszczalność metabolity te zaliczane są do związków mobilnych, w związku z czym mogą zanieczyszczać wody powierzchniowe i gruntowe. Metabolity te mogą pojawić się również w wodzie przeznaczonej do spożycia przez ludzi. Chociaż nie są one herbicydami, należy je monitorować, gdyż ich kumulacja i długotrwałe utrzymywanie się w wodzie może stanowić zagrożenie dla zdrowia człowieka. Celem niniejszego artykułu jest przedstawienie najnowszych doniesień literaturowych dotyczących zanieczyszczenia wody herbicydami ze szczególnym uwzględnieniem chloridazonu i jego metabolitów oraz wskazanie możliwości ich eliminacji z wody.
EN
Chloridazon was an herbicide used in sugar beet crops; inhibited the photosynthesis process of annual broad-leaved weeds. In recent decades, chloridazon has been considered harmiess, so farmers in many countries have used it. Chloridazon is broken down into two metabolites: chloridazon-desphenyl and chloridazon-methyl-desphenyl. As a result of their polarity and solubility, these metabolites are classified as mobile compounds, therefore, they can contaminate surface and groundwater.These metabolites may also occur in water intended for human consumption. Although chloridazon metabolites are not herbicides, they should be monitored because their accumulation and long-term persistence in water can pose a threat to human health.The purpose of this article is to present the latest literature reports on herbicide water contamination, with particular emphasis on chloridazon and its metabolites, and to indicate the possibility of their elimination from water.
EN
Surface water samples from the area of Munzur Stream in Türkiye (a Ramsar site) were evaluated for their suitability for irrigation and drinking purposes using different water quality indices. The human health risks were assessed as well. The study was conducted over a period of 24 months from January 2019 to December 2021 by taking samples from nine stations every month in order to determine the water quality of Munzur Stream, located in Tunceli. According to the results, Munzur Stream is in good condition in terms of the quality of drinking water and irrigation water. The concentrations of heavy metals such as Cu, Ni, Fe and Hg were high, though the water quality parameter according to Türkiye Ministry of Forestry and Water Affairs Surface Water Quality Regulations (TSWQR) was significantly lower than the permitted limits. In Munzur Stream, the irrigation water for all stations was reported to be excellent, good and suitable in terms of SAR, Na% and MH, respectively. The principal component analysis data formed the four principal components, explaining 98.22% of the total variance. The sources of pollution in this area include the rock types of the basin, soil erosion, domestic waste water discharge and agricultural flow of inorganic fertilisers.
EN
The study area of the Nida valley was examined to investigate variations in groundwater and surface water levels, as well as the interaction between them. In the valley, there were three branches. The two actives were the Nida River itself and the Smuga Umianowicka branch while the Stara Nida branch was dry during the measurement session. Over a 12-month period from June 2021 to June 2022, 7 monitoring points were equipped with piezometers, comprising 5 groundwater points and 2 surface water points. The monitoring frequency was set to 30 minutes. The results of this research indicate that there are significant differences in the water level at the same observed point at different times. This study demonstrates seasonal changes in both surface water and groundwater levels with higher levels in autumn and winter and lower levels in spring and summer, which are closely tied to the changes in meteorological conditions during the research period, such as precipitation and air temperature. The study results also indicate that during summer and winter at the Nida River and its riparian area, losing stream is the primary process occurring in the studied reach. Conversely, during autumn and spring, the main process is gaining stream. At the human-maintained Smuga Umianowicka branch and in its riparian area, losing stream is the main process during summer and autumn, and gaining stream is the main process during spring. During winter, losing stream and gaining stream processes can occur simultaneously, and neither process takes place mainly.
EN
The paper presents in form of a case study the results of 10-year long hydro-chemical studies on the Korzeń stream on which the “Skrzyszów” small storage reservoir was built. Studies aimed at evaluating the impact of the reservoir on the surface water quality in a Flysch stream. The basis for the analysis was results of 21 hydro-chemical water quality parameters, from the following groups of indicators: physical and acidity, oxygen and organic pollution, biogenic, salinity, metals. Indicators were determined in one-month intervals in two periods: 2005-2009 (before the reservoir was built) and 2015–2019 (after the reservoir was built). Obtained results were subjected to a statistical analysis. The trend analysis of changes was performed using the Mann-Kendall test or the seasonal Kendall test; significance of differences between indicator values from two periods was evaluated using the nonparametric Mann-Whitney U test. Results of analysis showed significant change trends of water quality parameters, in case of total iron concentration the trend was downward in both periods. Statistically significant differences between the values of definite majority of indicators were found in two analysed periods, indicating both favourable and unfavourable impact of the reservoir on water quality in the stream. Construction of the storage reservoir resulted in a significant change of physical and chemical indicators of water flowing in the stream. Random variation dynamics as well as tendencies and trends of changes over time have changed. In addition to modifying the stream hydro-chemical regime, the reservoir also affected the social and natural conditions.
EN
The aim of the study was to use regenerated activated carbon to adsorb phenol from a river. Coconut shell activated carbon was derived from used tap water filter cartridges. The activated carbon was carbonised and then activated with KOH at 200°C, under a nitrogen atmosphere. The resulting adsorbent was characterised on the basis of nitrogen adsorption by Brunauer-Emmett-Teller (BET), scanning electron microscopy (SEM) analysis and point of zero charge (pH PZC). The study of periodic adsorption included kinetic and equilibrium modelling, determined the effect of solution pH on efficiency and the possibility of regeneration and reuse of the adsorbent. The efficiency of phenol removal from model water was evaluated, followed by the possibility of their adsorption from a polluted river in Silesia Province. Phenol adsorption followed pseudo-second-order kinetics. The adsorbents showed high adsorption abilities, as determined by the Langmuir isotherm model. The model fits the experimental data well. The concentration of phenol in the river was in the range of 0.45-0.77 mg∙dm-3, which means that its value was at least five times higher than the standard values. The use of regenerated activated carbon from waste filter cartridges removed phenol from the river by 78% using optimal test parameters.
EN
The presence of microplastic pollution in coastal areas has garnered attention due to its detrimental impact on aquatic ecosystems and human health. In this study, our objective was to identify and characterize microplastics in the Banger River area of Pekalongan City, which is known for its numerous industrial activities, particularly batik small-medium industries. The extraction process involved filtration, drying, wet peroxide oxidation, density separation using NaI, and identification of microplastic particles. The shape, color, and size of the particles were characterized using a stereo microscope, while Fourier Transform Infra-Red Spectrometer and the hot needle method were employed for chemical structure analysis. Given that rivers serve as primary conduits for waste transport from land to sea, we conducted sampling at different times of the day. Our findings revealed an average of 0.61 ± 0.47 particles/m3 in the morning, 0.59 ± 0.67 particles/m3 in the afternoon, and 0.10 ± 0.02 particles/m3 in the evening. Among the microplastic polymers analyzed, we successfully identified polypropylene as one of the two predominant types. To establish a baseline for mitigating the release of plastic waste and microplastic residues into the environment, long-term monitoring is essential to evaluate the flow of plastic waste and microplastics from Indonesian rivers to the oceans.
EN
In hydrology and water resources engineering, predicting the flow coefficient is a crucial task that helps estimate the precipitation resulting in a surface flow. Accurate flow coefficient prediction is essential for efficient water management, flood control strategy development, and water resource planning. This investigation calculated the flow coefficient using models based on Simple Membership functions and fuzzy Rules Generation Technique (SMRGT) and an Adaptive Neuro-Fuzzy Inference System (ANFIS) model. The fuzzy logic methods are used to model the intricate connections between the inputs and the output. Statistical parameters such as the coefficient of determination (R2), the root mean square error (RMSE), the mean absolute error (MAE), and the mean absolute percentage error (MAPE) were used to evaluate the performance of models. The statistical tests outcome for the SMRGT model was (RMSE:0.056, MAE:1.92, MAPE:6.88, R2:0.996), and for the ANFIS was (RMSE:0.96, MAE:2.703, MAPE:19.97, R2:0.8038). According to the findings, the SMRGT, a physics-based model, exhibited superior accuracy and reliability in predicting the flow coefficient compared to ANFIS. This is attributed to the SMRGT’s ability to integrate expert knowledge and domain-specific information, rendering it a viable solution for diverse issues.
EN
The Nida valley study area underwent examination to investigate the hydrochemical components and the correlation between groundwater (GW) and surface water (SW). Over a 12-month period from November 2021 to October 2022, 9 monitoring points were established, consisting of 7 GW points and 2 SW points, with a monitoring frequency of once per month. The research findings indicate that the hydrochemical components and direction of GW flow in the study area can be classified into 3 distinct regions. The chemical composition is complex in areas near the Nida River, stable in the region near the Smuga Umianowicka branch, and different in other areas. It was observed that the SW in the Nida River and Smuga Umianowicka branch exhibits a relatively uncomplicated chemical composition due to minimal human impact in the natural area. However, dissimilarities between them were also identified and explained by the flow regulation of the dam built on the branch within the study area. The application of the Shapiro-Wilk test (α = 0.05) and Kruskal-Wallis test (α = 0.05) revealed statistically significant differences among the recorded hydrochemical component values throughout the measurement period. Furthermore, Pearson’s correlation coefficient analysis (α = 0.001) indicated correlations between the hydrochemical components of SW and GW in the riparian area and strong correlations among GW samples. Principal Component Analysis (PCA) identified significant dissimilarity and similarity between GW and SW samples based on their characteristics.
EN
The city of Taza, situated in Morocco, boasts a significant ecological heritage. However, a concerning practice of discharging untreated wastewater into the nearby Oueds has raised apprehensions about potential threats to public well-being. This research endeavors to discern the locations most adversely affected by pollution and subsequently assess their environmental condition. By conducting an extensive year-long analysis encompassing physicochemical and bacteriological aspects, we gathered a comprehensive dataset for appraising the surface water quality, utilizing the SEQ-WATER system as the evaluation framework. Four distinct sites emerged as particularly impacted: upstream of Oueds Jaouna and Taza, downstream of Oued Larbâa and adjacent to the “Julien” public dump, and at the confluence of Oueds Rhouireg and Dfali. Employing the GIS-SEQ integration, we meticulously gauged the physicochemical and bacteriological attributes of these sites. Our assessment unveiled readings that surpassed the established Moroccan benchmarks for surface water quality. Notably, the water exhibited pronounced turbidity and elevated levels of suspended particles, including nitrites and sulfates. Additionally, a notable organic load and microbial contamination involving fecal coliforms (E. coli) and intestinal enterococci were observed. These findings underscore the critical necessity for the implementation of efficient wastewater treatment measures within Taza, which would substantially safeguard both the populace and the surrounding ecosystem. It is imperative to conduct further in-depth investigations to validate these outcomes and devise comprehensive strategies aimed at mitigating the potential hazards linked with the compromised state of surface water.
EN
Oued Nfifikh is a coastal stream of the Bouregreg and Chaouia watershed (Morocco). It passes through many rural and urban areas and receives different types of liquid and solid discharges from anthropogenic activities adopted along the watercourse. This study aims to evaluate the physicochemical quality of the water from the most accessible sites upstream and downstream of Oued Nfifikh, along with highlighting the impact of human activities on these waters’ quality. For this purpose, water samples were collected and analyzed within normalized methods. Statistical analysis of the collected data shows significant spatial variations (pvalue < 0.05) for pH, electrical conductivity, nitrate and chloride, and for metallic trace elements (Zn, Fe, Ba, Mn, Cr and Al). Unlike (temperature, Pb, Ni, Cu and Cd), whose values do not present statistically significant variations (pvalue > 0.05). The study of the physicochemical quality reveals that the waters at the upstream are classed as good quality, except for site (S2), located at the upstream part of the river, it is affected by human activities. Consequently, its physicochemical composition is quite similar to that of waters of poor quality at the downstream sites. The Principal Component Analysis of the results followed by the Ascending Hierarchical Classification on the same data matrix allowed to regroup the sampling sites with similar characteristics into three distinct groups. A group of highly mineralized waters, a second group dominated by elements indicating urban pollution, and a group of waters with low mineral content and low metallic contamination indicating agricultural pollution.
EN
The authors conducted studies on the release rate of 222Rn from groundwater flowing out of a spring, from metamorphic reservoir rocks. This source gives rise to a stream about 205 m long. The activity concentration of Rn in the spring was about 700 Bq/dm33, took place at a distance of about 1 70-180 metres from the spring. With regard to the waterflow path, flowtime and the volume of water flowing through the cross-section of the tested stream, the exhalation coefficient of222Rn from water to atmospheric air is 3.80 Bq/dm3/m, 1.51 Bq/dm3/s and 1. 25 Bq/dm3/dm3, respctively. According to the authors, further research conducted in other springs occurring in other types of rocks and under different flow conditions (at different times of the year) will allow characterizing the dynamics of the process of222Rn release from groundwater through surface waters into the atmosphere. Perhaps this process can be described with a universal mathematical function.
EN
Today, the uncontrolled abstraction of surface water and groundwater resources has created adverse consequences, which include: extinction of living organisms, land subsidence, salinity of coastal aquifers, increased pumping energy. Therefore, the need to manage available water resources is felt more than ever. Among the various water uses (agriculture, drinking, and industry), agriculture accounts for the bulk of water consumption. Due to the climate change and the growing population, determining the appropriate strategy and technology for irrigation is necessary. In the current study, a simulation model is used to numerically simulate the dynamics of daily soil moisture during the potato crop growing season and to estimate crop production and economic benefits. For climatic data, daily observations of a meteorological station have been used. Results and analyses have been presented for all cases of micro and traditional irrigation methods and agricultural management strategies of non-stress irrigation, low irrigation, and rainfed cultivation. The results showed that in the non-stress irrigation method, crop production and net profit are almost equal in both traditional and micro methods. In the low irrigation method, microtechnology has made crop production and net profit 1.75 times more than traditional technology, which indicates the impact of irrigation technology on crop production.
EN
A study of the effect of subaquatic discharge of karst groundwater sources on the composition of the Vishera River, the largest tributary of the Kama River, was carried out. The study was carried out on the territory of the State Nature Reserve "Vishersky" and included the determination of the flow rate, temperature as well as chemical composition of natural waters. Six zones of karst groundwater discharge and their influence on the water regime of the Vishera river were studied in detail. It was shown that subaquatic sources in the places of their discharge, forming up to 36% of the river flow, significantly affect the temperature regime. A significant part of dissolved substances, primarily calcium ions and hydrocarbonate ions, as well as some trace elements (Li, Sr, V, Cr) enter the Vishery river with karst waters. The results of the study show that monitoring the composition and properties of groundwater discharged covertly in the river channel is an important part of the monitoring of water bodies of both protected and developed areas.
EN
The article presents the generalized results obtained from the analysis of oil pollution of surface waters in the fields of the Far North. The research considered the administrative territorial division of the Russian Federation, the territory of the Khanty-Mansi Autonomous Okrug – Yugra (KhMAO). The results of the study performed on the basis of field data on sampling for the year were presented. The influence of the hydrocarbon content in surface waters and snow cover was assessed. The aim of the work was to consider the snow cover as a natural source of pollutants, affecting the accumulation in surface waters and snow cover. The results obtained can be used for subsequent observations of snow cover and surface waters. The data obtained can serve as a basis for planning further research and developing the solutions for environmental protection in the Far North. The analysis of the dependencies between the indicators of hydrocarbon pollution in surface waters and snow cover was carried out using the methods of correlation and parametric multivariate regression analysis. The methods of geoinformation analysis and GIS technologies were also used in the work. It was revealed that the problem of the state of snow cover and its role as an indicator of atmospheric and soil pollution require further research. On the one hand, the snow cover detains metals, and polluted soil areas are formed locally, on the other hand, after the snow melts, the pollutants remaining on the surface with surface runoff enter rivers and are carried by the wind for quite long distances.
EN
Deformations of the channel are a consequence of the development of denudation processes in the basin area, increase in the volume of solid runoff and deposition of debris of the rock, its fractional redistribution in the channels, which especially increase during floods and flooding. They cause changes in the hydrological regime and structure of the river system, the destruction of residential and commercial buildings, as well as the infrastructure in the floodplain. Trends, magnitudes and intensity of deformations of riverbeds are formed by a complex of natural and man-made factors. Neglecting the planned and high-altitude displacements of riverbeds often leads to unpredictable consequences. Washing the shore can cause a gas or oil pipeline to rupture, leading to a strong explosion and fire, as well as oil pollution and environmental damage. Channel processes are associated with the washing of bridge piers, power lines, significant material losses and even human casualties during floods and flooding. The aim of the work is to analyze the development of channel processes in the basin of the river Stryi and forecast the deformation of its channel. The results of the analysis show that the riverbeds of Prykarpattia are very unstable and are characterized by intense erosion of the banks and bottom, which is caused by the influence of various factors. It is a man-made activity that includes the development of gravel quarries in floodplains and riverbeds and their straightening, runoff regulation, changes in forestry and land use. Natural factors, such as climate change and water runoff, etc., are also affected. It was found that the bed of the river Stryi does not have a stable shape, significantly changed the configuration, significantly reduced multi-sleeved and increased its straightness, and in some places the river changed its position by 60–80 meters. Restoration works carried out in some parts of the riverbed during this period were not effective enough. Water in different parts of the riverbed washes the shores, which causes dangerous landslides that occur directly near the riverbed. In these areas, it is necessary to more effectively carry out measures to regulate runoff and restore shore protection.
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