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Mechanisms of electrical conductivity, quantum capacity and negative capacitance effects in InSe (PTHQ) nanohybrid

Ivashchyshyn Fedir, Maksymych Vitaliy, Calus Dariusz, Klapchuk Myroslava, Baryshnikov Glib, Galagan Rostislav, Litvin Valentina, Chabecki Piotr, Bordun Ihor

Bulletin of the Polish Academy of Sciences. Technical Sciences

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2022

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Vol. 70, nr 1

art. no. e139958

EN

In this work, we present findings on the syntheses and study of properties of InSe < PTHQ > nanohybrid. The introduction of guest component in GaSe matrix leads to an increase in inhomogeneities, which is clearly confirmed by the strengthening of the low-frequency horizontal branch of Nyquist diagrams. A constant magnetic field counteracts this effect and changes the behavior of the impedance hodograph at low frequencies to the opposite. Illumination leads to a colossal increase in quantum capacitance, which is clearly demonstrated in the Nyquist diagram. For the synthesized InSe < PTHQ > nanohybrid the interesting behavior of the current-voltage characteristic is reported. As a result of studies of the synthesized InSe < PTHQ > nanohybrid the effect of “negative capacity” is observed, the magnitude of which can be controlled by the electric field. Based on the constructed impedance model and proposed N-barrier model, the physical mechanisms of the investigated processes are suggested.

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An in Situ Crystal Growth of Metal Organic Frameworks-5 on Electrospun PVA Nanofibers

Talmoudi H., Khenoussi N., Adolphe D., Said A. H., Schacher L.

Autex Research Journal

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2018

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Vol. 18, no. 3

308--313

EN

In this study, a simple, general and straightforward method for growing metal-organic frameworks (MOFs) crystals directly on nanofibers is presented. A chelating polymer was first blent with metal cation and then electrospun. The obtained nanofibers were immersed in a linker solution. Metal cations were released and the metal-organic frameworks crystals were grown on the fibers’ surface. In this work, this method was tested with polyvinyl alcohol as chelating polymer, Zn2+ as metal cation and Terephthalic acid as linker. The pair cation/linker corresponds to the MOF-5. The latter is a robust metal organic framework formed from Zn4O nodes with 1,4-benzodicarboxylic acid struts between the nodes. SEM images revealed that the MOF-5 nanocrystals have grown along the PVA/Zn2+ nanofibers that served as the crystals’ growth template by providing the Zn2+ ions. This result was also confirmed by infrared spectroscopy, which indicates the presence of characteristic bands of MOF-5 in the modified nanofibers spectrum. Moreover, the X-ray diffraction showed that MOF-5 material was well crystallized on the nanofibers surface according to a cubic symmetry with a space group Fm-3m and a lattice constant a = 25.8849 Å.

3

Routing problems based on HILS system platform

Adamski A.

LogForum

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2015

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Vol. 11, no. 1

87--98

EN

Background: The logistic systems are very complex socio-technical systems. In this paper the proposal of application of the hierarchical multi-layers system platform HILS approach for the solution of the complex vehicle routing problems is presented. The interactive system functional structure was proposed which by intelligent dedicated inter-layers interactions enables the professional solutions of these practical problems. To illustrate these capabilities the complex example of the real-time VRP-SPD-TW routing problem was presented in which upper layers offers the context-related real-time updating network specifications that stimulates the adequate routing parameters and specifications updating for problem solution in optimization layer. At the bottom dispatching control layer the DISCON (Dispatching CONtrol) method from public transport was adopted to logistics applications in which the actual routing is treated as obligatory reference schedule to be stabilized. The intelligence aspects are related among others to HILS based decomposition, context-related trade-offs between routing modifications and corrective dispatching control capabilities e.g. priority or route guidance actions. Methods: Decomposition of the vehicle routing problem for the HILS layers tasks creating the ILS system hierarchical structure. Dedicated solution method for the VRP-SPD-TW routing problem. The recognition of the control preferences structure by AHP-Entropy methods. DISCON and PIACON multi-criteria interacting control methods. Results: Original formulation and solution of the vehicle routing problem by system-wide approach with essential practical advantages: consistency, lack of redundancy, essential reduction of dimension, dedicated formulation, multi-criteria approach, exploration of the integration and intelligence features supported by the intelligent PIACON-DISCON methods control activities Conclusions: The presented proposal creates the professional approach to the solution of the crucial problems in logistics systems with the implementation of modern tools and enabling technologies.

PL

Wstęp: Zastosowano hierarchiczną wielowarstwową platformę systemową HILS do rozwiązywania złożonych problemów wyboru tras dla pojazdów logistycznych. Metody: Dekompozycja problemu wyboru tras na zadania warstw systemowych tworzących hierarchiczną strukturę ILS systemu. Dedykowana metoda rozwiązania problemu wyboru tras dla problemu VRP-SPD-TW . Metody rozpoznawania struktury preferencji sterowania wielokryterialnego AHP - Entropia. DISCON i PIACON metody optymalnego sterowania dyspozytorskiego i ruchu indywidualnego jedno/wielokryterialne. Wyniki: Sformułowano i rozwiązano oryginalny problem wyboru tras przy pomocy podejścia systemowego oferującego istotne zalety praktyczne, redukcja wymiarowości i redundancji, systemowe wielo-kryterialne podejście, eksploracja cech integracji i inteligencji wspomaganej inteligentnymi działaniami sterującymi. Wnioski: Proponowane podejście stanowi profesjonalne rozwiązanie kluczowych problemów spotykanych w systemach logistycznych z wykorzystaniem nowoczesnych narzędzi i technologii umożliwiających.

4

Modele hierarhicznych struktur w relacyjnych bazach danych o architekturze klient-serwer.

Czekalski P.

Studia Informatica

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2001

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Vol. 22, nr 3

115-129

PL

W artykule przedstawiono wybrane zagadnienia związane z wykorzystaniem struktur słownikowych w relacyjnych bazach danych oraz aplikacjach zarządzających bazami. Omówiono wykorzystanie struktur hierarchicznych jako prostego narzędzia pozwalającego użytkownikom na poruszenie się po strukturze oraz porównano techniki implementacji aplikacji klienta bazy. Omówienie oparto na elementach systemu rejestru usług medycznych i systemu informatycznego kas chorych.

EN

This article covers selected problems involved with hierarchical dictionaries implementation. It contains functionality and client implementation comparison, particularly simplicity and usability. The comparison is based on parts of Medical Services Registering System and software solutions for National Health Services.