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Analyzing a Sequence of Reactions by the De Donder Equation

Głowiński J., Tylus W., Hałat A.

Polish Journal of Chemistry

2001

Vol. 75, nr 1

105-114

In the kinetic analysis of the mechanism postulated simplified assumptions are often made. These assumptions are generally verified by comparing the simplified kinetic description with experimental data. In this study consideration is given to the idea of constructing a quantitative" measure for the "qualitative" assessment of the assumption (approximation), which makes it possible to examine its adequacy at an arbitrary moment of the reaction. The adopted measures are defined as criteria for steady-state and equilibrium (quasi-equilibrium) approximations.