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Wpływ zawilgoconego ditlenku węgla na korozję stali rurociągowej

Masłowski Mateusz, Czupski Marek, Wójcikowski Artur

Przemysł Chemiczny

2024

T. 103, nr 3

404--409

Przedstawiono informacje dotyczące procesów korozji stali podczas transportu ditlenku węgla w celu składowania go w formacjach złożowych. Opisano metodykę laboratoryjnego badania korozji stali w środowisku zawilgoconego CO₂, w warunkach temperatury i ciśnienia panujących na początku i na końcu rurociągu. Ocenie odporności na korozję poddano rurę stalową X65C wraz ze spoiną. Badania obejmowały ekspozycję próbek stali w środowisku zawilgoconego CO₂, a następnie analizę zmian masy oraz powierzchni stali w celu wyznaczenia szybkości korozji równomiernej oraz głębokości, szerokości i długości wżerów. Na podstawie wyników badań stwierdzono, że poddana testom stal X65C i spoina były całkowicie odporne na działanie ciekłego CO₂ zawierającego 50 ppmv lub 1000 ppmv wody.

Six X65C steel pipe samples, with or without weld, were kept in a wet CO₂ environment (500 and 1000 ppmv) under precisely defined conditions of temp. (4 and 30°C) and pressure (12 and 15 MPa) prevailing at the beginning and end of pipeline, for 10 days. The change in mass and surface image of the samples was analyzed to det. the uniform corrosion rate and pit size. The tested X65C steel and weld were resistant to liq. CO₂ contg. 50 ppmv and 1000 ppmv water because the detd. corrosion rate was less than 0.001 mm/year.

Estimation of temporary decommissioning impact on reliability and durability of oil pipelines

Poberezhny L., Martyniuk R., Stanetsky A., Poberezhna L., Tkach O., Hrytsanchuk A.

Journal of Achievements in Materials and Manufacturing Engineering

2019

Vol. 94, nr 1-2

22--31

Purpose: Due to changes in the volume of oil transportation, part of the pipelines must be temporarily decommissioned. The purpose of the work is theoretical and experimental study of pressure fluctuations during operation of oil pipelines and their impact on the durability of the pipeline material in work state and after temporary decommissioning (conservation). Design/methodology/approach: The results of oil pressure fluctuation research have given a chance to choose the terms of experimental research providing of the pipe metal mechanical features changes research during oil pipeline exploitation. Findings: Fatigue test modes are selected based on the calculations of the mathematical model developed. Experimental studies of the dependence of the fatigue strength of the pipe material on the conditions of operation have been carried out, which made it possible to determine the parameters of the fatigue curve of the samples. Has been defined that fatigue strength for the new metal pipe samples is more for 20-25% than for the metal samples which had the contacts with lime milk and for 30-40% more than for metal samples which were under exploitation. Research limitations/implications: In the future, more combination of "pipe material - preservation medium" should be explored to establish pain of general regularities. Practical implications: The probabilistic curves of the pipeline non-destruction are constructed, which will be used for practical calculations of the reliability and durability of the 13G1S-U steel pipelines. Originality/value: Mathematical model is made that describes non-stationary oil moves in oil pipeline, that has been caused by jump like changes of oil supply in oil pipeline, on this basis was defined, that oil pressure in oil pipeline provides within non stationary process in a range of 0.4-0.6 Hz frequency and amplitude fluctuation of pressure is 0.1-0.5 MPa.