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Immobilization of rambutan (Nephelium lappaceum) peel as a sorbent for Basic Fuchsin removal

Lee H.-J., Ong S.-T.

Environment Protection Engineering

2017

Vol. 43, nr 1

169--181

The potential of rambutan (Nephelium lappaceum) peel as a low-cost adsorbent in an immobilized condition to remove Basic Fuchsin from aqueous solution was studied. The effect of initial dye concentration, contact time, pH and adsorbent dosage for the dye removal was studied at room temperature (26±2 °C). Infrared spectrum of rambutan peel indicates the presence of C–O, –OH and C=C functional groups. The adsorption rate was found to be high at the first 30 min and the process reached equilibrium after 3 h with more than 80% of dye being removed. The uptake of Basic Fuchsin was more promising at pH slightly above 7. The study of sorption model and kinetic model showed that the adsorption of Basic Fuchsin on rambutan peel conformed to the Freundlich isotherm and pseudo-second order kinetics with a high correlation coefficient, R,sup>2 > 0.98. This indicates the Basic Fuchsin adsorbs chemically on the heterogeneous surface of rambutan peel. The maximum adsorption capacity determined from the Langmuir isotherm was 108.696 mg/g. It seems that rambutan peel has the potential to substitute activated carbon as an alternative low-cost adsorbent in the treatment of the dye effluent.

Chemical transformation of chromed leather wastes into environmentally harmless fibrous biomass

Malek A., Benotmane B., Aribi C., Hachemi M.

Environment Protection Engineering

2016

Vol. 42, nr 3

179--192

Chemical transformation of leather waste into chromium free biomass has been investigated. The conversion was performed by extracting the toxic metal. The effects of several influential factors on the process have been studied using design of experiments. Optimal conditions of chromium extraction have been determined. The collagen fiber of the biomass obtained has been analyzed by the Fourier transform infrared spectroscopy (FTIR). The chemical mechanism allowing this transformation has been suggested. The infrared analysis showed that the collagen fiber of the obtained biomass presents chemical composition similar to that of native collagen fiber of non-chromed leather. These results demonstrated the almost complete extraction of chromium from leather waste and the conversion of these latter into an environmentally harmless biomass.

Niechromatograficzne techniki instrumentalne w analizie olejów roślinnych

Gromadzka J., Wardencki W.

Analityka : nauka i praktyka

2009

nr 3

29-32