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Magnetic shielding tensors of sp-hybridized carbon nuclei

Gryff-Keller A.

Polish Journal of Chemistry

1998

Vol. 72, nr 2

154-162

Experimental data concerning shielding tensors of the sp hybridized carbons including our own recent results have been reviewed. It appears, that the most general feature of shielding parameters for such carbons forms a linear relationship between the perpendicular chemical shift component and the isotropic chemical shift. Deviation from that interdependence informs about a distortion of the symmetry of the electron distribution around the given carbon and indirectly about various intra- or intermolecular interactons.