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EN
Currently, a very big problem of cities in Europe and the world is air pollution with combustion products of car fuels, generation of heat and electricity. These impurities affect the microclimate of cities significantly. Pollution not only affects the area outside buildings, but getting into their interior through ventilation systems, which has an adverse effect on the indoor environment of buildings. High concentrations of CO 2, cause a weakening of concentration in working people, which affects the deterioration of safety and work efficiency. For assessing air quality improvement on “green roofs”, a field study of CO 2 content has been carried out on the “green roof” of a four-storey building, on a completely identical non-greened building, and on a highway with high-density traffic near them in Kiev. It was found that greening the roof significantly reduces the CO 2 content from 501 ppm on the road and 452 ppm on the roof without protection to 410-415 ppm. It improves the conditions in which people work and rest.
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EN
The fixation of CO2 in the form of inorganic carbonates, also known as mineral carbonation, is an interesting option for the removal of carbon dioxide from various gas streams. The captured CO2 is reacted with metal-oxide bearing materials, usually naturally occurring minerals. The alkaline industrial waste, such as fly ash can also be considered as a source of calcium or magnesium. In the present study the solubility of fly ash from conventional pulverised hard coal fired boilers, with and without desulphurisation products, and fly ash from lignite fluidised bed combustion, generated by Polish power stations was analysed. The principal objective was to assess the potential of fly ash used as a reactant in the process of mineral carbonation. Experimental were done in a 1 dm 3 reactor equipped with a heating jacket and a stirrer. The rate of dissolution in water and in acid solutions was measured at various temperatures (20 – 80ºC), waste-to-solvent ratios (1:100 – 1:4) and stirrer speeds (300 – 1100 min -1). Results clearly show that fluidised lignite fly ash has the highest potential for carbonation due to its high content of free CaO and fast kinetics of dissolution, and can be employed in mineral carbonation of CO2.
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