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Fractional Composition of Organic Matter and Properties of Humic Acids in the Soils of Drained Bogs of the Siedlce Heights in Eastern Poland

Becher Marcin, Tołoczko Wojciech, Godlewska Agnieszka, Pakuła Krzysztof, Żukowski Emil

Journal of Ecological Engineering

2022

Vol. 23, nr 4

208--222

The studied bogs of the Siedlce Heights in eastern Poland are currently undergoing decession. In the course of pedological studies, a significant modification of the structure of soil profiles caused by the murshing process was found. The total contents of carbon and nitrogen values (TC/TN = 11.1–17.3) obtained in the study, as well as slight acidification (pHKCl 5.42–6.15) indicate the eutrophy of the studied soil environment, high biological activity and a significant degree of organic matter processing as a result of the processes of mineralization and humification. In addition, the upper levels covered by the process of murshing, compared to peat, are characterized by lower carbon content and, most often, similar nitrogen content. In the studied soils, humic substances are mostly represented by the fraction of humic acids. As a consequence, high values of the quotient expressing quantitative relations between soil humus fractions (HAs/FAs) were noted. For all profiles, the highest share of fulvic acids was recorded in turf murshic levels (M1). The occurrence of the most mature humic acids was found in the peat levels not covered by secondary transformation processes after dehydration.

Phosphorus Accumulation in the Dehydrated Peat Soils of the Liwiec River Valley

Becher Marcin, Pakuła Krzysztof, Jaremko Dawid

Journal of Ecological Engineering

2020

Vol. 21, nr 5

213--220

The aim of the research was to complement the knowledge on profile distribution and accumulation of phosphorus forms in the soils changed under the influence of secondary organic matter transformation process in dehydrated peatlands. The soil research was carried out in the upper Liwiec river valley in the middle-east of Poland. In the soil material taken from the moorsh (M1, M2, M3) and peat (O) horizons of the Murshic Histosols, the physical and chemical properties were determined and the soil phosphorus fractions with different activity in the environment by sequential extraction method were separated. The profile distribution of the total phosphorus content (TP) and values of carbon/phosphorus (TC/TP) ratio were characteristic for dehydrated peat soils included in the secondary transformation process (M1>M2>M3>O). This process also increased the contribution of the available phosphorus forms (NH4Cl-P), forms bound on the surface of iron (III) and manganese (IV) oxides and hydroxides (redox-P), as well as mineral (mHCl-P) and organic (oHCl-P) forms separated by 0.5 M HCl. Significant accumulation of the phosphorus compounds in the moorsh horizons of the investigated soils can be considered as a potential threat to the natural environment of the studied area due to the risk of decomposition of the phosphorus compounds when the area will be rehydrated.