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LOcal Rovibrational Instability in a water Molecule

Konarski J., Mańkowski M.

Polish Journal of Chemistry

2003

Vol. 77 / nr 11

1615-1623

Using the stability matrix method, the occurrence of locally unstable states in the water molecule has been shown. Detailed analysis of this problem reveals a dependence of the state stability on the rotational quantum numbers Jand k, as well as on the rotation about the z axis perpendicular to the molecular plane, i.e. on the rotation at which the Coriolis coupling reaches a maximum.