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Prognosis of energetic compounds stability in solid phase

Manelis G. B., Nazin G. M., Prokudin V. G.

Central European Journal of Energetic Materials

2009

Vol. 6, nr 1

31-44

Results of the analysis and specification of phenomenological models of the monomolecular reactions running homogeneously in volume of undisturbed crystal lattice or localized on its defects are presented. It is shown, that within the limits of these models it is possible to calculate with satisfactory accuracy the ratio of rate constants in liquid and solid phases KT = kliq/ksol, and thus on known kliq to predict ksol, describing stability of substance.