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Unusual echinoid resting trace records change in the position of the redox boundary (Palaeogene of the Lesser Caucasus in Georgia)

Uchman Alfred, Lebanidze Zurab, Kobakhidze Nino, Beridze Tamar, Makadze Davit, Lobzhanidze Koba, Khutsishvili Sophio, Chagelishvili Rusudan, Koiava Kakha, Khundadze Nino

Acta Geologica Polonica

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2022

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Vol. 72, no. 3

317--330

EN

The first recognition of a tracemaker responding to a temporary shift in the redox boundary is recognized. This is recorded by a new trace fossil, Sursumichnus orbicularis igen. et isp. nov., which is established for mound-like structures on the upper surfaces of sandstone beds from the Borjomi Flysch (upper Paleocene–lower Eocene) in the Lesser Caucasus (Georgia). It is connected with the spatangoid echinoid burrow Scolicia de Quatrefages, 1849 and interpreted as a resting trace of the same tracemaker produced after moving up from a deeper position within the sediment. The resting is caused by an episode of unfavourable conditions related to shallowing of the redox boundary. The trace fossil is a component of the Nereites ichnofacies.

2

Redox conditions, glacio-eustasy, and the status of the Cenomanian-Turonian Anoxic Event: new evidence from the Upper Cretaceous Chalk of England

Jeans Christopher V., Wray David S., Williams C. Terry, Bland David J., Wood Christopher J.

Acta Geologica Polonica

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2021

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Vol. 71, no. 2

103--152

EN

The nature of the Cenomanian–Turonian Oceanic Anoxic Event (CTOAE) and its δ13 C Excursion is considered in the light of (1) the stratigraphical framework in which the CTOAE developed in the European shelf seas, (2) conclusions that can be drawn from new detailed investigations of the Chalk succession at three locations in England, at Melton Ross and Flixton in the Northern Province where organic-rich ‘black bands’ are present, and at Dover in the Southern Province (part of the Anglo-Paris Basin) where they are absent, and (3) how these conclusion fit in with the present understanding of the CTOAE. The application of the cerium anomaly method (German and Elderfield 1990) at Dover, Melton Ross and Flixton has allowed the varying palaeoredox conditions in the Chalk Sea and its sediments to be related to the acid insoluble residues, organic carbon, δ18O (calcite), δ13C (calcite), δ13C (organic matter), Fe 2+ and Mn2+ (calcite), and P/TiO2 (acid insoluble residue). This has provided evidence that the initial stages of the δ13C Excursion in England were related to (1) a drop of sea level estimated at between 45 and 85 metres, (2) influxes of terrestrial silicate and organic detritus from adjacent continental sources and the reworking of exposed marine sediments, and (3) the presence of three cold water phases (named the Wood, Jefferies and Black) associated with the appearance of the cold-water pulse fauna during the Plenus Cold Event. Conditions in the water column and in the chalk sediment were different in the two areas. In the Northern Province, cerium-enriched waters and anoxic conditions were widespread; the δ13C pattern reflects the interplay between the development of anoxia in the water column and the preservation of terrestrial and marine organic matter in the black bands; here the CTOAE was short-lived (~0.25 Ma) lasting only the length of the Upper Cenomanian Metoicoceras geslinianum Zone. In the Southern Province, water conditions were oxic and the δ13C Excursion lasted to the top of the Lower Turonian Watinoceras devonense Zone, much longer (~1.05 Ma) than in the Northern Province. These differences are discussed with respect to (1) the Cenomanian–Turonian Anoxic Event (CTAE) hypothesis when the ocean-continent-atmosphere systems were linked, (2) limitations of chemostratigraphic global correlation, and (3) the Cenomanian-Turonian Anoxic Event Recovery (CTOAER), a new term to define the varying lengths of time it took different oceans and seas to recover once the linked ocean-continent-atmosphere system was over. The possibility is considered that glacio-eustasy (the glacial control hypothesis of Jeans et al. 1991) with the waxing and waning of polar ice sheets, in association with the degassing of large igneous provinces, may have set the scene for the development of the Cenomanian-Turonian Anoxic Event (CTAE).

3

Palaeoenvironmental significance of iron carbonate concretions from the Bathonian (Middle Jurassic) ore-bearing clays at Gnaszyn, Kraków-Silesia Homocline, Poland

Witkowska M.

Acta Geologica Polonica

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2012

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Vol. 62, no. 3

307-324

EN

Iron carbonate concretion horizons are characteristic features of the Bathonian (Middle Jurassic) claystone-mudstone succession at Gnaszyn. They occur in single horizons, which generally represent the same genetic type. The siderite concretions are the main type of iron carbonate concretions at Gnaszyn; a second type is represented by phosphate-siderite concretions. On the basis of the fieldwork, and their petrographical and mineralogical characteristics, the genesis of the concretions and their palaeoenvironmental significance is discussed. The results of this study (based on the localization, mode of occurrence, mineralogy of iron carbonate concretions and also the textural relationship between the concretions and host sediment layers) suggest an early diagenetic origin of the concretions. The preferential occurrence of the concretion horizons in single layers in the ambient sediments was associated with particular conditions of their deposition and early diagenesis, favored by a slower sedimentation rate and more intense bioturbation, and related primarily to the greater availability of reactive iron ions. From the viewpoint of physicochemical conditions the horizons with iron carbonate concretions in the study area reflect the redox boundary between oxic/bioturbated and anoxic/non-bioturbated zones. The conditions favoring the formation of such horizons was possibly due to longer periods of diminished sedimentation rate when the redox boundary remained in the same position within the sediment.

4

Framboidy pirytowe jako wskaźniki paleośrodowiska

Zatoń M., Rakociński M., Marynowski L.

Przegląd Geologiczny

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2008

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Vol. 56, nr 2

158-164

EN

The problemof application of pyrite framboids in reconstructions of the redox conditions is presented. The characteristics of pyrite framboids, their origin and principles of application in paleoenvironmental interpretations are given. The pyrite framboid diameter distribution as indicators of redox conditions was presented on the examples of the Middle Jurassic (Upper Bajocian-Lower Bathonian) ore-bearing clays of the Polish Jura, and Upper Devonian (Middle and Upper Famennian) dark grey and black shales from Kowala (Holy Cross Mountains). It has been shown, that during the sedimentation of the ore-bearing clays, the pyrite framboids formed in the sediment, below the oxic water column; however, some episodic oscillation around the dysoxic conditions cannot be entirely excluded. During the sedimentation of the Middle Famennian dark grey shales, the redox conditions at the sea-floor oscillated around dysoxia. In both examples, the framboids are characterized by wide range of their diameters and the presence of large, >10 "my"m, framboids. On the contrary, the Upper Famennian black shales, representing the Hangenberg event, were deposited below the euxinic conditions in the water column. It is indicated by a high frequency of small-size framboids, far below 6 "my"m in diameter, and the lack of the large ones. The overlying shales, on the other hand, show the transition to more oxic conditions. The redox conditions interpreted above are in agreement with the independent biomarker analyses and paleontological observations.

5

Badanie zmian potencjału redoks podczas hodowli wgłębnej A. niger

Głuszcz P.

Zeszyty Naukowe. Inżynieria Chemiczna i Procesowa / Politechnika Łódzka

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1999

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Z. 26

251-256

PL

Zbadano zmiany potencjału redoks podczas hodowli wgłębnej pleśni A. niger w laboratoryjnym fermentorze zbiornikowym oraz wieżowym typu air-lift, na podłożu zawierającym sacharozę. Obserwowane przebiegi zmian potencjału redoks wykazywały charakterystyczne minima i maksima, przy czym wystąpienie minimum było związane z przejściem z fazy wzrostu biomasy do fazy produkcji kwasu cytrynowego. Wydajność produktu zależała od amplitudy zmian potencjału redoks oraz od typu fermentora. Najlepsze efekty hodowli uzyskano w bioreaktorze typu air-lift.

EN

Changes of the redox potential during submerged cultivations of A. niger in stirred-tank and air-lift fermentors on sucrose were investigated. The characteristic profiles of the redox potential with a minimum at the beginning of the citric acid production phase were observed. The yield of the product depended on the type of the fermentor and on the amplitude of redox potential changes. The best results were obtained in the air-lift bioreactor. In the fermentations with the redox potential regulated according to the specific time profile high citric acid concentration and good reproducibility of final results.