The theoretical and experimental researches of mechanisms of interaction of the fire-extinguishing aerosol with a flame are carried out. The factors of heterogeneous inhibition of a flame-free-radicals (O, OH, H, CHX) on a crystal surface of the inorganic salts being the basic components of fire-extinguishing powders and aerosols are measured with the use of laboratory equipment. The semi-empirical calculations by methods of quantum chemistry for heterogeneous inhibition reactions of buming are executed. The universal mechanism of influence on a flame of a crystal surface of a fire-extinguishing powder particle is offered.
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