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Tentative Identification of C3No Radical Luminescence in Solid Krypton

Crépin C., Monéron L., Douin S., Boyé-Péronne S., Kołos R., Turowski M., Gronowski M., Sepioł J., Bénilan Y., Gazeau M. C.

Polish Journal of Chemistry

2008

Vol. 82, nr 4

741-749

A product of cyanoacetylene photodissociation in Kr matrices gives rise to visible emission bands tentatively identified as due to the fluorescence and to the phosphorescence of the C3No radical. This assignment, which involves the low lying ~A 2P state as the final one for both emissions, is based on the isotopic substitution study and on former theoretical predictions.