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pi-Electron Communication Through the Metal Valence Shell –W, Mo and Fe Complexes Containing Maleimidato Moiety

Palusiak M.

Polish Journal of Chemistry

2007

Vol. 81, nr 5-6

903-909

The characterization of carbonyl–metal and maleimidato–metal bonding has been performed using the topological analysis of electron distribution function estimated for molecules of ( 5-C5H5)M(CO)3( 1-N-maleimidato) (M = W, Mo) and ( 5-C5H5)Fe(CO)2( 1-N-maleimidato). The Atoms in Molecules (AIM) approach has been applied for characterization of and -components of the metal–ligand bonds. The -electron communication between trans-placed ligands is present in Wand Mo derivatives. The ellipticity parameter is suggested to be a useful and highly sensitive parameter in the analysis of the metal–ligand bonding